Abstract
The densities and speeds of sound in pentan-1-ol + octan-1-ol, pentan-1-ol + nonane and hexane + nonane binary systems have been measured over the whole composition range from 293.15 to 313.15 K. For comparison, literature data for the hexane + octan-1-ol mixture have also been analyzed. The quantities determined have been plotted as functions of temperature and composition. The excess molar volumes and excess molar compressions have been interpeted on the basis of the homomorph concept.
Similar content being viewed by others
References
H. Ogawa and S. Murakami, J. Solution Chem. 16, 315(1987).
H. D. Pflug and G. C. Benson, Can. J. Chem. 46, 287(1986).
G. C. Benson and H. D. Pflug, J. Chem. Eng. Data 15, 382(1970).
A. Aucejo, M. C. Burguet, R. Munoz, and M. Santchotello, J. Chem. Eng. Data 41, 508(1996).
I. Brown, W. Fock, and F. Smith, Aust. J. Chem. 17, 1106(1964).
A. J. Treszczanowicz and G. C. Benson, J. Chem. Thermodyn. 12, 173(1980).
Heintz, B. Schmittecker, D. Wagner, and R. N. Lichtenthaler, J. Chem. Eng. Data 31, 487(1986).
T. P. Iglesias, J. L. Legido, L. Romani, and M. I. Paz Andrade, Phys. Chem. Liquids 25, 135(1993).
C. Franjo, E. Jimenez, T. P. Iglesias, J. L. Legido, and M. I. Paz Andrade, J. Chem. Eng. Data 40, 68(1995).
E. Jimenez, C. Franjo, L. Segade, J. L. Legido, and M. I. Paz Andrade, J. Chem. Eng. Data 42, 262(1997).
J. Nath and J. G. Pandey, J. Chem. Eng. Data 42, 128(1997).
B. E. de Cominges, M. M. Pineiro, T. P. Iglesias, J. L. Legido, and M. I. Paz Andrade, J. Chem. Thermodyn 30, 1147(1998).
E. Mascato, L. Mosteiro, M. M. Pineiro, J. Garcia, T. P. Iglesias, and J. L. Legido, J. Chem. Eng. Data 45, 1154(2000).
M. I. Aralaguppi, T. M. Aminabhavi, R. H. Balundgi, and S. S. Joshi, J. Phys. Chem. 95, 5299(1991).
B. Orge, A. Rodriguez, J. M. Canosa, G. Marino, M. Iglesias, and J. Tojo, J. Chem. Eng. Data 44, 1041(1999).
J. Ortega and J. S. Matos, Mater. Chem. Phys. 15, 415(1986).
K. N. Marsh, Data Bases for Chemistry and Engineering, TRC Thermodynamic Tables, A&M University, Texas (1994).
T. M. Aminabhavi, V. B. Patil, M. I. Aralaguppi, and H. T. S Phayde, J. Chem. Eng. Data 41, 521(1996).
F. Sarmiento, M. Paz Andrade, J. Fernandez, R. Bravo, and M. Pintos, J. Chem. Eng. Data 30, 321(1985).
M. Diaz Pena and G. Tardajos, J. Chem. Thermodyn. 11, 441(1979).
B. Orge, M. Iglesias, and J. Tojo, J. Chem. Eng. Data 40, 260(1995).
T. M. Aminabhavi and V. B. Patil, J. Chem. Eng. Data 43, 504(1998).
M. Iglesias, B. Orge, and J. Tojo, J. Chem. Thermodyn. 27, 253(1995).
A. J. Treszczanowicz and G. C. Benson, J. Chem. Thermodyn. 10, 967(1978).
O. Kiyohara and G. C. Benson, J. Chem. Thermodyn. 11, 861(1979).
C. Yanes, A. Maestre, P. Perez-Tejeda, and J. J. Calvente, J. Chem. Eng. Data 38, 512(1993).
W. Marczak, J. Chem. Eng. Data 44, 621(1999).
E. Zoreębski and M. Zoreębski, Papers of the World Congress on Ultrasonics, Berlin, p. 547(1995).
W. Marczak, J. Acoust. Soc. Amer. 102, 2776(1997).
T.-H. Van and D. Patterson, J. Solution Chem. 11, 793(1982).
D. Patterson, J. Solution Chem. 23, 105(1994).
D. Patterson, Thermochim. Acta 267, 15(1995).
P. de St. Romain, Huu Tra Van, and D. Patterson, J. C. S. Faraday I 75, 1700(1979).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Gepert, M., Ernst, S. Interpretation of the Excess Molar Volumes and Excess Molar Compressions of Pentan-1-ol + Octan-1-ol Mixtures on the Basis of the Homomorph Concept. Journal of Solution Chemistry 32, 831–852 (2003). https://doi.org/10.1023/B:JOSL.0000003152.24858.98
Issue Date:
DOI: https://doi.org/10.1023/B:JOSL.0000003152.24858.98