Abstract
Densities and apparent molar volumes of aqueous 2-chloroethanol were determined at temperatures from 15.0 to 34.4°C using digital densimetry. The results of the volumetric measurements have been used to calculate the following thermodynamic quantites at 25°C: V 2 o = 55.05 ± 0.02 cm3-mol−1, (∂V 2 o/∂T)p = 0.01486 ± 0.00318 cm3-K−1-mol−1, and (∂2 V 2 o/∂T 2)p = 0.02972 ± 0.00318 cm3-K−2-mol−1. Partial molar volumes of transfer from water to 1 mol-dm−3 2-chloroethanol have also been determined for L-glycine, L-alanine, L-serine, L-glutamic acid, and L-aspartic acid at 35.0°C. The transfer results have been explained in terms of the nature of the interactions of the groups in the solute and solvent. Hydration numbers of L-glycine and L-alanine have also been calculated in aqueous 2-chloroethanol.
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References
P. D. Thomas and K. A. Dill, Protein Sci. 2, 2050(1993).
K. Shiraki, K. Nishikawa, and Y. Goto, J. Mol. Biol. 245, 180(1995).
M. Buck, S. E. Radford, and C. M. Dobson, Biochemistry 32, 669(1993).
P. Fan, C. Bracken, and J. Baum, Biochemistry 32, 1573(1993).
A. T. Alexandrescu, Y. L. Ng, and C. M. Dobson, J. Mol. Biol. 235, 587(1994).
L. de Polverino, E. Frare, R. Gottardo, and A. Fontana, Proteins Struct. Funct. Genet. 49, 385(2002).
V. Militello, M. Leone, A. Cupane, R. Santucci, and A. Desideri, Biophys. Chem. 19, 121(2002).
T. Konno, J. Iwashita, and K. Nagayamma, Protein Sci. 9, 564(2000).
M. J. Dyson, G. Merukta, J. P. Waltho, T. A. Lerner, and P. E. Wright, J. Mol. Biol. 226, 795(1992).
M. D. Bruch, M. M. Dhingra, and L. M. Gierasch, Proteins Struct. Funct. Genet. 10, 130(1992).
M. Gasset, M. A. Baldwin, D. H. Lloyd, J. M. Gabriel, D. M. Holtzman, F. Cohen, R. Fletterick, and S. B. Prusiner, Proc. Natl. Acad. Sci. USA 89, 10940(1992).
H. Zhang, K. Kaneko, J. T. Nguyen, T. L. Livshits, M. A. Baldwin, F. E. Cohen, T. L. James, and S. B. Prusiner, J. Mol. Biol. 250, 514(1995).
C. J. Barrow, A. Yasuda, P. T. Kenny, and M. G. Zagorski, J. Mol. Biol. 225, 1075(1992).
S. J. Wood, B. Maleeff, T. Hart, and R. Wetzel, J. Mol. Biol. 256, 870(1996).
F. E. Jones, J. Res. Natl. Bur. Stand. (US) 83, 419(1978).
N. Kishore and R. Marathe, J. Chem. Thermodyn. 32, 413(2000).
D. G. Archer, J. Phys. Chem. Ref. Data 21, 793(1992).
J. E. Desnoyers, Pure Appl. Chem. 54, 1469(1982).
G. R. Hedwig, J. F. Reading, and T. H. Lilley, J. Chem. Soc. Faraday Trans. 87, 1751(1991).
T. V. Chakilian, A. P. Sarvazyan, and K. J. Breslauer, J. Phys. Chem. 97, 13017(1993)
D. P. Kharakoz, Biophys. Chem. 34, 115(1989).
M. Iqbal and M. Maleeullah, Can. J. Chem. 68, 725(1990).
F. Franks, M. A. Quickenden, D. S. Reid, and B. Watson, Trans. Faraday Soc. 66, 582(1970).
P. A. Leduc, J. C. Fortier, and J. E. Desnoyers, J. Phys. Chem. 78, 1217(1974).
J. F. Reading, I. D. Watson, and G. R. Hedwig, J. Chem. Thermodyn. 22, 159(1990).
M. E. Friedman and H. A. Scheraga, J. Phys. Chem. 69, 3795(1965).
T. Nakajima, T. Komutsu, and T. Nakoyama, Bull. Chem. Soc. 48, 783(1975).
C. Jolicoeur and G. Lacroise, Can. J. Chem. 54, 624(1976).
S. Terasawa, H. Itsuki, and S. Arakawa, J. Phys. Chem. 79 (1975).
D. M. Alexander, J. Chem. Engg. Data 4, 252(1959).
M. HÄckel, G. R. Hedwig, and H-J. Hinz, Biophys. Chem. 73, 163(1998).
V. K. Buckin, A. P. Sarvazyan, and D. P. Kharakoz in Water in Disperse System, B. V. Deryagin, N. V. Churev and F. D. Ovcharenko, eds. (Moscow, Khimiya 1989), p. 45.
S. Pajik, C. Klofutar, and M. Kac, J. Chem. Engg. Data 35, 41(1990).
R. W. Gurney, Ionic Process in Solution (McGraw Hill, New York 1953).
H. S. Frank and M. W. Evans, J. Chem. Phys. 13, 507(1945).
H. L. Friedman and C. V. Krishnan, in Water-A Comprehensive Treatise, F. Franks, ed. (Plenum, New York, (1973), Chap. 1.
F. Shahidi, P. G. Farrell, and J. T. Edwards, J. Solution Chem. 5, 807(1976).
F. J. Millero, A. Lo Surdo, and C. Shin, J. Phys. Chem. 82, 784(1978).
E. Berlin and M. J. Pallansch, J. Phys. Chem. 72, 1887(1968).
F. J. Millero, G. K. Lepple, and E. V. Haff, J. Phys. Chem. 78, 1636(1974).
S. Li., X. Hu, R. Lin, W. Sang, and W. Fang, J. Solution Chem. 4, 365(2001).
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Munde, M.M., Kishore, N. Volumetric Properties of Aqueous 2-Chloroethanol Solutions and Volumes of Transfer of Some Amino Acids and Peptides from Water to Aqueous 2-Chloroethanol Solutions. Journal of Solution Chemistry 32, 791–802 (2003). https://doi.org/10.1023/B:JOSL.0000003149.57001.bc
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DOI: https://doi.org/10.1023/B:JOSL.0000003149.57001.bc