Abstract
The crystal structure of 17-(1-adamantyl)amino-6,7,9,10-tetrahydro-17H-dibenzo[d, m][1,3,6,9,12,2]pentaoxaphosphacyclotetradecine-17-oxide, C26H32NO6P (I), was determined by single crystal X-ray diffraction. The monoclinic structure of I (space group P21 /n; a=10.951(2), b=16.730(3), c=13.255(3) Å, β=99.22(2)°, Z=4) was solved by direct methods and refined anisotropically by the full-matrix least-squares method; R=0.042 for all independent 4197 reflections (CAD-4 automatic diffractometer, MoKα). The geometrical parameters of molecule I (bond lengths and bond and torsion angles) were determined with a good accuracy.
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Cheklov, A.N. Crystal and Molecular Structure of 17-(1-Adamantyl)amino-6,7,9,10-tetrahydro-17H-dibenzo[d, m]-[1,3,6,9,12,2]pentaoxaphosphacyclotetradecine-17-oxide. Journal of Structural Chemistry 45, 169–174 (2004). https://doi.org/10.1023/B:JORY.0000041519.04404.51
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DOI: https://doi.org/10.1023/B:JORY.0000041519.04404.51