Skip to main content
SpringerLink
Log in

Crystal Structures of Anhydrous Potassium, Rubidium, and Cesium Hypophosphites

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Crystals of anhydrous K, Rb, and Cs hypophosphites have been obtained. The structures of these compounds were determined by X-ray diffraction analysis. The structure in general is a packing of layers of metal cations and hypophosphite anions coordinated to them. In all compounds, the hypophosphite anion performs the function of a bridge between four cations in a layer. Each oxygen atom is linked to two cations. The compounds RbH2PO2 and CsH2PO2 are isostructural.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. T.J.R. Weakley, Acta Crystallogr., B35, No.1, 42–45 (1979).

    Google Scholar 

  2. P.A. Tanner, L. Yu-Long,and T.C.W. Mak, Polyhedron, 16, No.3, 495–505 (1997).

    Google Scholar 

  3. L.A. Aslanov, V.M. Ionov, M.A. Porai-Koshits,et al., Neorg.Mater., 11, No.1, 117–119 (1975).

    Google Scholar 

  4. T. Matsuzaki and Y. Iitaka, Acta Crystallogr., B25, No.10, 1932–1938 (1969).

    Google Scholar 

  5. T.J.R. Weakley and W.W.L. Watt, ibid., B35, No.12, 3023/3024 (1979).

    Google Scholar 

  6. P.A. Tanner, T.-H. Sze, T.C. Mak,et al., J.Cryst.Spectr.Res., 22, No.1, 25–30 (1992).

    Google Scholar 

  7. P.A. Tanner, M.D. Faucher,and T.C.W. Mak, Inorg.Chem., 38, No.26, 6008–6023 (1999).

    Google Scholar 

  8. M. Catti, Acta Crystallogr., B35, No.5, 1041–1046 (1979).

    Google Scholar 

  9. N.V. Romanova and N.V. Demidenko, Usp.Khim., 44, No.12, 2150–2170 (1975).

    Google Scholar 

  10. G. Brun, A. Norbert, and M. Caucanas-Dumail, Rev.Chim.Miner., 9, 581–589 (1972).

    Google Scholar 

  11. Enraf-Nonius (1989).CAD-4 Software,CD4CA0 (Version 5.0),CADDAT (Version 5.1),Enraf-Nonius,Delft,The Netherlands.

  12. G.M. Sheldrick, SHELXS-97 and SHELXL-97, Göttingen (1997).

  13. R.W. Harrison, R.C. Thompson,and J. Trotter, J.Chem.Soc.A:Inorg.,Phys.,Theor., 1775–1780 (1966).

  14. W. Granier, J. Durand, L. le Cot, and J.L. Galigne, Acta Crystallogr., B31, 2506/2507 (1975).

    Google Scholar 

  15. J. Trotter and S.H. Withlow, J.Chem.Soc.A:Inorg.,Phys.,Theor., 1383–1386 (1967).

Download references

Author information

Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    M. I. Naumova, N. V. Kuratieva, D. Yu. Naumov & N. V. Podberezskaya

Authors
  1. M. I. Naumova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. V. Kuratieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. Yu. Naumov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. V. Podberezskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Naumova, M.I., Kuratieva, N.V., Naumov, D.Y. et al. Crystal Structures of Anhydrous Potassium, Rubidium, and Cesium Hypophosphites. Journal of Structural Chemistry 45, 107–113 (2004). https://doi.org/10.1023/B:JORY.0000041508.85103.9f

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JORY.0000041508.85103.9f

Search

Navigation