Abstract
Molecular structure of N,N-dimethyldiaziridine was studied by gas-phase electron diffraction and quantum-chemical methods. It is confirmed that the molecule has a trans conformation, but the structural parameters r(endo-C–N) 1.448(2) Å, r(exo-C–N) 1.468(2) Å, and r(N–N) 1.514(6) Å differ substantially from the results of our previous electron diffraction study.
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Atavin, E.G., Golubinskii, A.V., Popik, M.V. et al. Gas-Phase Electron Diffraction and Quantum-Chemical Studies of the Molecular Structure of N,N-dimethyldiaziridine. Journal of Structural Chemistry 44, 784–789 (2003). https://doi.org/10.1023/B:JORY.0000029815.03903.b7
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DOI: https://doi.org/10.1023/B:JORY.0000029815.03903.b7