Skip to main content
SpringerLink
Log in

Calculation of Spectroscopic Constants for the Ground Electronic States of KRb and RbCs Molecules

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The vibrational, rotational, and centrifugal constants have been calculated for the ground electronic states of KRb and RbCs molecules. The calculation is performed using the semiempirical potential curves constructed in a wide range of internuclear distances. The estimated spectroscopic constants are compared with experimental data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. D. E. Johnson and I. G. Eden, JOSA, 2 No.5, 721-728 (1985).

    Google Scholar 

  2. S. I. Vetchinkin and I. M. Umanskii, Opt. Spektrosk., 2 No.1, 29-33 (1991).

    Google Scholar 

  3. A. V. Glushkov, V. A. Efimov, E. D. Gopchenko, et al., ibid., 84 No.5, 747-752 (1998).

    Google Scholar 

  4. A. D. Smirnov, Zh. Fiz. Khim., 76 No.2, 284-290 (2002).

    Google Scholar 

  5. A. D. Smirnov, ibid., 77 No.3, 478-483 (2003).

    Google Scholar 

  6. A. D. Smirnov, Vestn. Mosk. Gos. Tekhn. Univ. Baumana, Ser. Est. Nauk, No. 1, 105-115 (1999).

    Google Scholar 

  7. A. D. Smirnov, Zh. Fiz. Khim., 73 No.8, 1404-1410 (1999).

    Google Scholar 

  8. A. D. Smirnov, ibid., 74 No.7, 1266-1272 (2000).

    Google Scholar 

  9. A. D. Smirnov, ibid., No. 10, 1823-1827.

  10. A. D. Smirnov, Opt. Spektrosk., 89 No.2, 223-227 (2000).

    Google Scholar 

  11. A. J. Ross, C. Effantin, P. Crozet, and E. Boursey, J. Phys. B, 23, L247-L251 (1990).

    Google Scholar 

  12. C. Amiot and J. Verges, J. Chem. Phys., 112 No.10, 7068-7074 (2000).

    Google Scholar 

  13. T. Gustavsson, C. Amiot, and J. Verges, Chem. Phys. Lett., 143 No.1, 101-105 (1988).

    Google Scholar 

  14. H. Kato and H. Kobayashi, Chem. Phys., 79, 123-129 (1983).

    Google Scholar 

  15. J. N. Huffaker, J. Chem. Phys., 64, 3175-3181 (1976).

    Google Scholar 

  16. A. D. Smirnov, Opt. Spektrosk., 81 No.3, 390-396 (1996).

    Google Scholar 

  17. A. A. Radtsig and B. M. Smirnov, Handbook in Atomic and Molecular Physics [in Russian ], Atomizdat, Moscow (1980).

    Google Scholar 

  18. A. D. Smirnov, Opt. Spektrosk., 78 No.4, 615-621 (1995).

    Google Scholar 

  19. F. Jenc and B. A. Brandt, J. Mol. Spectrosc., 154, 226-230 (1992).

    Google Scholar 

  20. A. R. Allouche, M. Korek, K. Fakhereddin, et al., J. Phys. B, 33, 2307-2316 (2000).

    Google Scholar 

  21. Gisele Hadinger, Gerold Hadinger, S. Magnier, and Aubert-Frecon, J. Mol. Spectrosc., 175, 441-444 (1996).

    Google Scholar 

  22. D. L. Albritton, W. J. Harrop, A. L. Schmeltekopf, and R. N. Zare, ibid., 46, 25-36 (1973).

    Google Scholar 

  23. A. Kratzer, Z. Phys., 3, 289-296 (1920).

    Google Scholar 

  24. E. C. Kemble, R. T. Birge, W. F. Colby, et al., Molecular Spectra in Gases, National Research Council, Washington, DC (1930), p. 57.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. E. Bauman Moscow State Technical University, Russia

    A. D. Smirnov

Authors
  1. A. D. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Smirnov, A.D. Calculation of Spectroscopic Constants for the Ground Electronic States of KRb and RbCs Molecules. Journal of Structural Chemistry 44, 757–762 (2003). https://doi.org/10.1023/B:JORY.0000029811.46828.0e

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JORY.0000029811.46828.0e

Search

Navigation