Skip to main content
SpringerLink
Log in

Crystal Structure Refinement for Potassium(2.2.2-cryptand)thiocyanate Monohydrate

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The crystal structure of potassium(2.2.2-cryptand)thiocyanate monohydrate, [K+(2.2.2-Crypt)]·SCN- ·H2O, has been refined by XRD analysis: space group P2/c, a=11.290(2), b=8.308(2), c=14.360(2) Å, β=109.97(2)°, Z=2; 3680 unique reflections, R=0.051. Using a different structural model with a twice shorter crystallographic a axis compared to the original work gave much more precise structural data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. J. Giusti, G. G. T. Guarini, P. Orioli, and P. Paoletti, Thermochim. Acta, 162, No.1, 99-105 (1990).

    Google Scholar 

  2. A. N. Chekhlov, Zh. Strukt. Khim., 44, No.2, 374-379 (2003).

    Google Scholar 

  3. D. Moras, B. Metz, and R. Weiss, Acta Crystallogr., B29, No.3, 388-395 (1973).

    Google Scholar 

  4. G. M. Sheldrick, The SHELX-97 Manual, University of Göttingen (1997).

  5. International Tables for Crystallography, Vol. C, Kluwer, Dordrecht (1992).

  6. F. Voegtle and E. Weber (eds.), Host —Guest Complex Chemistry. Macrocycles. Synthesis, Structures, Applications, Springer, Berlin (1985).

    Google Scholar 

  7. R. D. Shannon, Acta Crystallogr., A32, No.5, 751-767 (1976).

    Google Scholar 

  8. L. Pauling, The Nature of the Chemical Bond, Cornell University Press, Ithaca (1960).

    Google Scholar 

  9. A. Bondi, J. Phys. Chem., 68, No.3, 441-451 (1964).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka

    A. N. Chekhlov

Authors
  1. A. N. Chekhlov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chekhlov, A.N. Crystal Structure Refinement for Potassium(2.2.2-cryptand)thiocyanate Monohydrate. Journal of Structural Chemistry 44, 711–715 (2003). https://doi.org/10.1023/B:JORY.0000017951.15068.81

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JORY.0000017951.15068.81

Search

Navigation