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Internal Mobility, Structure, Phase Transitions, and Ionic Conductivity in Thallium Fluoroantimonates(III) TlSb4F13 and TlSb3F10

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Abstract

Internal mobility in TlSb4F13 (I) and TlSb3F10 (II) was studied by 19F NMR spectroscopy in the temperature range 210-450 K. Types of ionic motion in the fluoride subsystem were determined. Phase transitions resulting in modifications with high ionic (superionic) conductivity above 420 K were established for both compounds (385-425 K). Using impedance spectroscopy, we studied the electrophysical properties of I and II in the temperature range 290-425 K (σ∼ 1.1×10-3 and 1.0× 10-3 S/cm for I and II, respectively; T=425 K).

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Authors and Affiliations

  1. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok

    V. Ya. Kavun, A. A. Udovenko & L. A. Zemnukhova

  2. Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk

    N. F. Uvarov

Authors
  1. V. Ya. Kavun
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  2. N. F. Uvarov
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  3. A. A. Udovenko
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  4. L. A. Zemnukhova
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Kavun, V.Y., Uvarov, N.F., Udovenko, A.A. et al. Internal Mobility, Structure, Phase Transitions, and Ionic Conductivity in Thallium Fluoroantimonates(III) TlSb4F13 and TlSb3F10 . Journal of Structural Chemistry 44, 605–612 (2003). https://doi.org/10.1023/B:JORY.0000017936.71867.fb

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  • DOI: https://doi.org/10.1023/B:JORY.0000017936.71867.fb

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