Abstract
Experimental studies of Raman scattering and the infrared reflection spectra of lithium tetraborate crystals were carried out within a broad temperature range with various polarization geometries. The crystals studied are characterized by record values of radiation resistance, transparence within a broad spectral range including the ultraviolet region, and nonlinear optical properties. A group-theoretical analysis of the vibrational spectra of this crystal was performed and fundamental vibrational terms were assigned to the symmetry types of the point group as well as the polarizations of the corresponding modes. The effective Raman cross section was measured and was found to be one order of magnitude higher than those of the known crystals, in which the stimulated Raman scattering (SRS) was observed. The nonlinear optical and electrooptical coefficients were evaluated and were found to be consistent with the results of independent measurements. The effect of a drastic increase in the intensity of quasi-elastic light scattering at 253 K was registered. It was associated with the phase transition that consists of the disordering of lithium ions with respect to the rigid skeleton. The formation energy for Frenkel defects in the lithium sublattice and the activation energy of the ionic conduction when heating the sample were calculated from the obtained temperature dependences of the intensity of quasielastic and hyper-Rayleigh light scattering.
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C. Chen, Y. Wu, and R. Li, J. Cryst. Growth, 99, 790 (1990).
T. Shiosaki, M. Adachi, and A. Kawabata, Proc. IEEE, 455 (1986).
R. Komatsu, T. Sugawara, K. Sassa, et al., Appl. Phys. Lett., 70, 3492 (1997).
I. Naray-Szabo, Inorganic Crystal Chemistry, Akademiai Kiado, Budapest (1969).
W. H. Zachariasen, Acta Cryst., 17, 749 (1964).
H. König and A. Hoppe, Z. Anorg. Allg. Chem., 439, 71 (1978).
J. Krogh-Moe, Acta Cryst., 15, 190 (1962).
A. U. Sheleg and E. M. Zub, Kristallografia, 44, 905 (1999).
J. Krogh-Moe, Acta Cryst., B24, 179 (1968).
M. Natarajan, R. Faggiani, and I. D. Brown, Cryst. Struct. Comm., 8, 367 (1979).
S. F. Radaev, L. A. Muradian, L. F. Malakhova, et al., Kristallografia, 15, 1400 (1989).
T. Hahn (Ed.), International Tables for Crystallography, Kluwer Academic Publishers, Dordrecht-Boston-London (1995).
J. D. Garrett, M. I. Natarajan, and J. E. Greedan, J. Cryst. Growth., 41, 225 (1977).
V. V. Zaretskii and Ya. V. Burak, Fiz. Tverd. Tela, 31, 80 (1989).
K. Ya. Borman and Ya. V. Burak, Izv. Akad. Nauk, Neorg. Mater., 26, 440 (1990).
E. M. Zub, Fiz. Tverd. Tela, 39, 1461 (1997).
A. S. Bhalla, L. E. Cross, and R. W. Whatmore, Jap. J. Appl. Phys., 24, 727 (1985).
Yu. N. Ivanov, Ya. V. Burak, and K. S. Aleksandrov, Fiz. Tverd. Tela, 32, 3379 (1990).
A. B. Kaplun and A. B. Meshalkin, Neorg. Mater., 35, 1349 (1999).
B. S. R. Sastry and F. A. Hummel, J. Am. Ceram. Soc., 41, 7 (1957).
Z. Shuquing, H. Chaoen, and Z. Hongwu, J. Cryst. Growth, 99, 805 (1990).
S.-J. Fan, W. Wang, J.-J. Xiang, and J.-X. Hu, J. Cryst. Growth, 99, 811 (1990).
V. Vezin, T. Sugawara, R. Komatsu, and S. Uda, Jap. J. Appl. Phys., 36, 5950 (1997).
R. Komatsu, T. Sugawara, T. Sugihara, and S. Uda, Jap. J. Appl. Phys., 34, 5467 (1995).
Ya. V. Burak, J. Cryst. Growth, 186, 302 (1998).
A. Yu. Kuznetsov, M. V. Kuznetsov, I. N. Ogorodnikov, et al., Fiz. Tverd. Tela, 36, 845 (1994).
C. Chen and Y. Wu, J. Opt. Soc. Am. B, 6, 616 (1989).
A. B. Sobolev, A. Yu. Kuznetsov, I. N. Ogorodnikov and A. V. Kruzhalov, Fiz. Tverd. Tela, 36, 1517 (1994).
Y.-N. Xu and W. Y. Ching, Phys. Rev. B, 41, 5471 (1990).
B. Wu, N. Chen, C. Chen, et al., Optics Lett., 14, 1080 (1989).
Ya. V. Burak, Ya. O. Dovgii, and I. V. Kityk, Fiz. Tverd. Tela, 31, 275 (1989).
O. T. Antonyak, Ya. V. Burak, I. T. Lyseiko, et al., Opt. i Spektrosk., 61, 550 (1986).
A. Yu. Kuznetsov, L. I. Isaenko, A. V. Kruzhalov, et al., Fiz. Tverd. Tela, 41, 57 (1999).
Ya. V. Burak, G. M. Gitskailo, I. T. Lyseiko, et al., Ukr. Fiz. Zh., 32, 1509 (1987).
Ya. V. Burak, V. M. Gaba, I. T. Lyseiko, et al., Ukr. Fiz. Zh., 36, 1638 (1991).
S. Furusawa, O. Chikagawa, S. Tange, et al., J. Phys. Soc. Japan, 60, 2691 (1991).
T. Y. Kwon, J. J. Ju, H. K. Kim, et al., Mater. Lett., 27, 317 (1996).
F. Zernike and J. E. Midwinter, Applied Nonlinear Optics: Basics and Applications, Wiley, New York (1973).
V. Petrov, A. F. Rotermund, F. Noack, et al., J. Appl. Phys., 84, 5887 (1998).
A. S. Bhalla, L. E. Cross, and R. W. Whatmore, Jap. J. Appl. Phys., 24, 727 (1985).
S. Furusawa, S. Tange, Y. Ishibashi, K. Miwa, J. Phys. Soc. Japan, 59, 2532 (1990).
M. Maeda, H. Tachi, K. Honda, and I. Suzuki, Jap. J. Appl. Phys., 33, 1965 (1994).
A. E. Aliev, Ya. V. Burak, and I. T. Lyseiko, Izv. Akad. Nauk, Neorg. Mater., 26, 1991 (1990).
M. B. Salamon (Ed.), Physics of Superionic Conductors, Springer-Verlag, New York (1979).
A. E. Aliev, I. N. Kholmanov, and P. K. Khabbibulaev, Dokl. Akad. Nauk, Fizika, 365, 178 (1999).
D. P. Button, L. S. Mason, H. L. Muller, and D. R. Uhlmann, Sol. State Ionics, 9&;10, 585 (1983).
S. F. Radaev, N. I. Sorokin, and I. V. Simonov, Fiz. Tverd. Tela, 33, 3597 (1991).
N. P. Tekhanovich, A. U. Sheleg, and Ya. V. Burak, Fiz. Tverd. Tela, 32, 2513 (1990).
A. E. Aliev, V. F. Krivorotov, and P. K. Khabbibulaev, Fiz. Tverd. Tela, 39, 1548 (1997).
A. U. Sheleg, T. I. Dekola, N. P. Tekhanovich, and A. M. Luginetz, Fiz. Tverd. Tela, 39, 624 (1997).
L. Bohaty, S. Haussuhl, and J. Liebertz, Cryst. Res. Technol., 24, 1159 (1989).
I. M. Sil'verstova, P. A. Senyuschenkov, V. A. Lomonov, and Yu. V. Pisarevskii, Fiz. Tverd. Tela, 31, 311 (1989).
A. E. Aliev, Ya. V. Burak, V. V. Vorob'ev, et al., Fiz. Tverd. Tela, 32, 2826 (1990).
A. A. Sehery and D. J. Somerford, J. Phys.: Cond. Matter, 1, 2279 (1989).
A. E. Aliev and R. R. Valetov, Fiz. Tverd. Tela, 34, 3061 (1992).
G. L. Pault and W. Taylor, J. Phys. C: Solid State Phys., 15, 1753 (1982).
S. Furusawa, S. Tange, Y. Ishibashi, K. Miwa, J. Phys. Soc. Japan, 59, 1825 (1990).
T. K. Berko, Ya. O. Dovgii, I. V. Kytik, et al., Ukr. Fiz. Zh., 38, 39 (1993).
Ya. V. Burak, Ya. O. Dovgii, and I. V. Kityk, Zh. Prikl. Spektroskop., 52, 126 (1990).
V. T. Adamiv, T. K. Berko, I. V. Kytik, et al., Ukr. Fiz. Zh., 37, 368 (1992).
V. S. Lebedev and V. D. Lysov, Prib. Tekh. Eksp., No. 6, 97 (1975).
S. S. Kurochkin, KAMAK-VEKTOR Systems [in Russian], Energoatoimizdat, Moscow (1981).
Yu. N. Potapovich, S. A. Popov, A. V. Vdovin, and V. I. Pastukhov, Vestnik Dnepropetrovskogo Universiteta. Fizika. Radiofizika., 53 (1994).
W. T. Eadie et al., Statistical Methods and Experimental Physics,North-Holland, Amsterdam (1971).
V. S. Gorelik, “On the anomalies of the spectral intensity of inelastic light scattering near the phase transition point in crystals,” in: M. M. Sushchinsky (Ed.), Inelastic Light Scattering in Crystals, Proceedings of the Lebedev Physical Institute [in Russian], Nauka, Moscow (1987), Vol. 180, p. 180.
G. N. Zhizhin, B. N. Mavrin, and V. F. Shabanov, Optical Vibrational Spectra of Crystals [in Russian], Nauka, Moscow (1984).
T. Kurosawa, J. Phys. Soc. Japan, 16, 1298 (1961).
M. V. Belousov, Fiz. Tverd. Tela, 15, 1206 (1973).
G. Andermann, A. Caron, and D. A. Rows, J. Opt. Soc. Am., 55, 1210 (1965).
E. A. Vinogradov, G. N. Zhizhin, I. I. Khammadov, et al., Fiz. Tverd. Tela, 24, 103 (1982).
I. Freund, Phys. Rev. Lett., 21, 1404 (1968).
M. E. Lines and A. M. Glass, Principles and Applications of Ferroelectrics and Related Materials, Clarendon Press, Oxford (1977).
S. Yu. Stefanovich and Yu. N. Venevtsev, Izv. Akad. Nauk SSSR, Ser. Fiz., 41, 537 (1977).
S. Kielich, Molekularna Optyka Nieliniowa [in Polish], PWN, Warszawa-Poznań (1977).
V. N. Moiseenko, A. V. Vdovin, and J. V. Burak, Proc. SPIE, 2648, 523 (1995).
V. N. Moiseenko, A. V. Vdovin, and J. V. Burak, “Studying the Raman Scattering Intensity Fluctations Origin in Li2B4O7 Crystals under the Temperature Variation,” in: Proc. of the International Autumn School-Conference for Young Scientists “Solid state Physics: Fundamentals and Applications” (SSPFA'95), Uzhgorod, Ukraine (1995), p. 43.
H. Poulet and J. P. Mathieu, Vibrational Spectra and Symmetry of Crystals, Gordon and Breach, Paris (1970).
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Mir, Moscow (1991).
T. C. Damen, S. P. S. Porto, and B. Tell, Phys. Rev., 142, 570 (1966).
S. P. S. Porto, J. A. Giordmane, and T. C. Damen, Phys. Rev., 147, 608 (1966).
V. N. Moiseenko, A. V. Vdovin, and Ya. V. Burak, Opt. i Spectrosk., 81, 620 (1996).
V. N. Moiseenko, V. S. Gorelik, J. V. Burak, A. V. Vdovin, “Raman Scattering Study of Incommensurate Li2B4O7 Crystals,” in: Proc. of the XIVth International Conference on Raman Spectroscopy, Hong Kong (1994), p. 361.
A. N. Lazarev, A. P. Mirgorodskii, and I. S. Ignat'ev, Vibrational Spectra of Complex Oxides [in Russian], Nauka, Leningrad (1975).
A. M. Heyns, K.-J. Range, and M. Wildenauer, Spectrochimica Acta, 46A, 1621 (1990).
S. D. Ross, Spectrochimica Acta, 28A, 1555 (1972).
A. N. Lazarev, Vibrational Spectra and the Structure of Silicates [in Russian], Nauka, Leningrad (1968).
B. Orel, M. Klanjsek, V. Moiseenko, et al., Phys. Stat. Sol. (b), 128, 53 (1985).
C. N. R. Rao, H. S. Randhawa, N. V. R. Reddy, and D. Chakravorty, Spectrochim. Acta, 31A, 1283 (1975).
F. Gervais, Optics Commun., 22, 116 (1977).
L. K. Vodopyanov, E. A. Vinogradov, and V. S. Vinogradov, Fiz. Tverd. Tela, 16, 849 (1974).
F. Gervais, Solid State Commun., 18, 191 (1976).
J. C. Phillips, Rev. Mod. Phys., 42, 317 (1970).
W. D. Jonston, Jr., Phys. Rev. B, 1, 3494 (1970).
I. P. Kaminow and E. H. Turner, Phys. Rev. B, 5, 1564 (1972).
V. S. Gorelik, O. G. Zolotukhin, and M. M. Sushchinsky, Zh. Prikl. Spektrosk., 28, 945 (1978).
V. S. Gorelik, O. G. Zolotukhin, and M. M. Sushchinsky, Fiz. Tverd. Tela, 22, 1024 (1980).
V. N. Moiseenko and V. S. Gorelik, Kratkie Soobshch. Fiz., No. 3, 20 (1992).
V. S. Gorelik and M. M. Sushchinsky, Fiz. Tverd. Tela, 11, 3340 (1969).
V. N. Moiseenko, A. V. Vdovin, V. S. Gorelik, and Ya. V. Burak, Kratkie Soobshch. Fiz., No. 2, 3 (2000).
V. N. Moiseenko, A. V. Vdovin, and M. P. Dergachov, Proc. SPIE, 4069, 36 (2000).
V. N. Moiseenko, A. V. Vdovin, and Ya. V. Burak, “Light Scattering Peculiarities Near the Phase Transition Point in Li2B4O7 Crystals,” in: Abstracts of the VIth Ukrainian-Polish Meeting on Phase Transitions and Ferroelectric Physics, Dnepropetrovsk, Ukraine (1998), p. 61.
V. N. Moiseenko, A. V. Vdovin, and Ya. V. Burak, “Nonlinear Optical Phenomena in Li2B4O7 Crystals,” in: Abstracts of the Inernational Scientific Conference “Optics of Crystals” (OC-2000), Mozyr, Belarus (2000), p. 42.
P. Toledano and J.-C. Toledano, Phys. Rev. B, 25, 1946 (1982).
Yu. A. Izyumov and V. N. Syromyatnikov, Phase Transitions and Symmetry of Crystals [in Russian], Nauka, Moscow (1984).
V. N. Moiseenko, A. V. Vdovin, V. S. Gorelik, and Ya. V. Burak, Kratkie Soobshch. Fiz., No. 10, 30 (1998).
A. G. Christy, Acta Cryst., B51, 753 (1995).
V. G. Bar'yakhtar, Solid State Physics: Encyclopaedia [in Russian], Naukova Dumka, Kiev (1998), p. 652.
V. N. Moiseenko, A. V. Vdovin, and M. P. Dergachev, Visnik Dnipropetrov'skogo Universitetu. Fizika, Radioelektronika., 1, 153 (1998).
V. N. Moiseenko, A. V. Vdovin, and Ya. V. Burak, “About an Opportunity of Phase Transition in Li2B4O7 Pyroelectric Crystals,” in: Proc. of the XVth International Conference on Raman Spec-troscopy, Pittsburg (1996), p. 1008.
V. L. Ginzburg, U. I. Goldberg, V. A. Golovko, et al., Light Scattering Close to the Phase Transition Points [in Russian], Nauka, Moscow (1990).
A. D. Bruce and R. A. Cowley, Structural Phase Transitions, Taylor and Francis, Philadelphia, Pa. (1981).
S. Ma, Modern Theory of Critical Phenomena, Benjamin, Reading, Mass. (1976).
V. N. Moiseenko, A. V. Vdovin, and Ya. V. Burak, “Temperature Anomalies in Raman Spectra Close to the Translation Phase Transition in Li2B4O7 Crystals,” in: Book of Abstracts of the XVth All-Russian Conference on Physics of Ferroelectrics (VKS-XV) [in Russian], Rostov-on-Don (1999), p. 92.
A. V. Vdovin, V. N. Moiseenko, and Ya. V. Burak, “On the Temperature Anomalies in Raman Spectra of Li2B4O7 Crystals,” in: Book of Abstracts of the First Ukrainian School-Workshop on the Physics of Ferroelectrics and Related Materials [in Ukrainian], L'viv, Ukraine (1999), p. 39.
K. S. Nak, H. C. Sung, R. L. Ae, and N. K. Jung, New Phys. (Korean Physical Society), 35, 670 (1995).
A. V. Rakov, “Studies of the Brownian rotary motion of molecules of condenced matter by Raman scattering and infrared absorption methods,” in: D. V. Skobeltsyn (Ed.), Studies on Molecular Spectroscopy, Proceedings of the Lebedev Physical Institute [in Russian], Nauka, Moscow (1964), Vol. 27, p. 111.
Yu. S. Kuz'minov, Ferroelectric Crystals for Control of Laser Emission [in Russian], Nauka, Moscow (1982).
A. F. Witt and H. C. Gatos, J. Electrochem. Soc., 113, 808 (1966).
Yu. S. Kuz'minov, Electrooptic and Nonlinear-Optical Crystal of Lithium Niobate [in Russian], Nauka, Moscow (1987).
A. A. Ballman, S. K. Kurts, and H. Brown, J. Cryst. Growth, 10, 185 (1971).
R. C. Miller, J. Phys. Soc. Japan, 28,Suppl. 1, 15 (1970).
J. p. van der Ziel and N. Bloembergen, Phys. Rev., 135, A1662 (1964).
V. D. Sal'nikov, S. Yu. Stefanovich, V. V. Chechkin, et al., Fiz. Tverd. Tela, 16, 196 (1974).
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Gorelik, V.S., Vdovin, A.V. & Moiseenko, V.N. Raman and Hyper-Rayleigh Scattering in Lithium Tetraborate Crystals. Journal of Russian Laser Research 24, 553–605 (2003). https://doi.org/10.1023/B:JORR.0000004168.99752.0e
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DOI: https://doi.org/10.1023/B:JORR.0000004168.99752.0e