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Novel Organometallic Aromatic Azo Polyesters Based on Ferrocene

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Abstract

Some ferrocene containing aromatic azo polyesters were prepared by condensing 1,1′-ferrocenedicarbonyl chloride with different azo groups containing aromatic diols, which were synthesized by diazotization coupling reaction from aromatic diamines. The polymeric products were separated as two portions on the basis of their solubility and subsequently characterized by their elemental analysis and FTIR spectral studies. Thermal properties of the products were measured by differential scanning calorimetry and thermogravimetry and the activation energies of pyrolysis were calculated using Horowitz and Metzger's method. The molecular weights of the soluble portions were determined by gel permeation chromatography (GPC) and these portions were also characterized by their inherent viscosities and UV-Vis spectroscopic studies.

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Authors and Affiliations

  1. Department of Chemistry, Quaid-i-Azam University, Pakistan

    Zareen Akhter, Muhammad Saif ullah Khan & Mubasher A. Bashir

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  1. Zareen Akhter
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  2. Muhammad Saif ullah Khan
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Akhter, Z., Khan, M.S.u. & Bashir, M.A. Novel Organometallic Aromatic Azo Polyesters Based on Ferrocene. Journal of Inorganic and Organometallic Polymers 14, 253–267 (2004). https://doi.org/10.1023/B:JOIP.0000048030.44827.cc

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