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Ru(II)(η6-p-cymene) Complexes Supported on Linear Chiral and Achiral Poly(spirophosphazene-pyridine) Copolymers

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Abstract

The reaction in dichloromethane at room temperature of the polyspirophosphazene copolymer {[NP(O2C12H8)]0.7[NP(OC5H4N)2]0.3} n (1) (O2C12H8=2,2′dioxybiphenyl) with [Ru2(η 6-p-cymene)2Cl4] gives the polymer supported organometallic complex {[NP(O2C12H8)]0.7[NP(OC5H4N-Ru(η 6-p-cymene)Cl2)2]0.3} n (2). Similarly the chiral phosphazene {[NP(O2C20H12)]0.9[NP(OC5H4N)2]0.1} n (3) (O2C20H12=R-2,2′-dioxy,1′1′-binaphthyl) reacts with the appropriate amount of the Ru precursor to give the related polymeric complex {[NP(O2C20H12)]0.9[NP(OC5H4N)(OC5H4N-Ru(η 6-p-cymene)Cl2]0.1} n (4) as an orange solid. Carrying out the reaction of 3 with the Ru precursor in acetone at room temperature using 0.35 equivalents of Ru per pyridine site, gives the crosslinked yellow material with formula {[NP(O2C20H12)]0.9[NP(OC5H5N)2]0.1[Ru(η 6-p-cymene)Cl2]0.07]} n (5), that may contain cationic [Ru(η 6-p-cymene)Cl]+ units trapped in the rigid interior of a chiral network.

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REFERENCES

  1. F. Ciardelli, E. Tsuchida, and D. Wöhrle, Macromolecule-Metal Complexes (Springer, Berlin, 1996).

    Google Scholar 

  2. (a) P. E. Garrou and B. C. Gates, in Synthesis and Separation using Functional Polymers, D. C. Sherrington and P. Hodge, eds. (Wiley, New York, 1988), Chap. 3, pp. 123-147. (b) C. U. Pittman, Jr., in Comprehensive Organometallic Chemistry, G. Wilkinson, F. G. A. Stone, and E. W. Abel, eds. Pergamon Press, London, 1982, Vol. 8, Chap. 55, pp. 553-611.

    Google Scholar 

  3. G. A. Carriedo, L. Fernandez Catuxo, F. J. García Alonso, and P. Gómez Elipe, J. Organomet. Chem. 503, 59(1995).

    Google Scholar 

  4. G. A. Carriedo, F. J. García Alonso, P. Gómez Elipe, C. Díaz Valenzuela, and N. Yutronic, J. Chil. Chem. Soc. 48, 25(2003).

    Google Scholar 

  5. G. A. Carriedo, F. J. García Alonso, P. A. González, and P. Gómez Elipe, Polyhedron 18, 2853(1999).

    Google Scholar 

  6. G. A. Carriedo, F. J. García Alonso, P. A. González, C. Díaz Valenzuela, and N. Yutronic, Polyhedron 21, 2579(2002).

    Google Scholar 

  7. G. A. Carriedo, F. J. García Alonso, J. L. García Alvarez, C. Díaz Valenzuela, and N. Yutronic, Polyhedron 21, 2587(2002).

    Google Scholar 

  8. C. Díaz, P. Castillo, G. A. Carriedo, P. Gómez Elipe, and F. J. García Alonso, Macromol. Chem. Phys. 203, 1912(2002).

    Google Scholar 

  9. G. A. Carriedo, F. J. García Alonso, A. Presa, J. Gimeno, and P. Crochet, submitted for publication.

  10. P. Hesemann and J. J. E. Moreau, Tetrahedron: Asymmetry 11, 2183-2194 (2000).

    Google Scholar 

  11. G. A. Carriedo, F. J. García Alonso, and A. Presa-Soto, Eur. J. Inorg. Chem. 4341(2003).

  12. M. A. Bennet, T.-N. Huang, T. W. Matheson, and A. K. Smith, Inorg. Synth. 21, 75(1982).

    Google Scholar 

  13. M. A. Bennet, M. I. Bruce, and T.W. Matheson, in Comprehensive Organometallic Chemistry, G. Wilkinson, F. G. A. Stone, and E. W. Abel, eds. (Pergamon Press, Oxford, 1982), Vol. 4, Chap. 32, pp. 797.

    Google Scholar 

  14. H. R. Allcock, K. D. Lavin, N. M. Tollefson, and T. Evans, Organometallics 2, 267-275, (1983).

    Google Scholar 

  15. M. T. R. Laguna, M. P. Tarazona, G. A. Carriedo, F. J. García Alonso, J. I. Fidalgo, and E. Saíz, Macromolecules 35, 7505-7515 (2002).

    Google Scholar 

  16. H. R. Allcock, A. A. Dembek, and E. H. Klingenberg, Macromolecules 24, 5208(1991).

    Google Scholar 

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Authors and Affiliations

  1. Depto Qca. Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, C/Julián Claveria S/N, Oviedo, 33071, Spain

    Gabino A. Carriedo, Francisco J. García Alonso & Alejandro Presa

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  1. Gabino A. Carriedo
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  2. Francisco J. García Alonso
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  3. Alejandro Presa
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Correspondence to Gabino A. Carriedo.

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Carriedo, G.A., García Alonso, F.J. & Presa, A. Ru(II)(η6-p-cymene) Complexes Supported on Linear Chiral and Achiral Poly(spirophosphazene-pyridine) Copolymers. Journal of Inorganic and Organometallic Polymers 14, 29–37 (2004). https://doi.org/10.1023/B:JOIP.0000016756.45895.a8

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