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Polymer Complexes XLV. Spectral Studies on Metal-Ligand Bonding in Novel Poly-Schiff Base Complexes

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Abstract

Polymer complexes derived from cinnamaldehyde and 2-substituted aniline with Cu(II), Pd(II), Pt(II), UO2(II), Rh(III), Ru(III), and Pd(IV) have been synthesized and characterized by IR, electronic, EPR, 1H-NMR, and 13C-NMR spectra, as well as by elemental analysis, thermogravimetry, and magnetic susceptibility measurements. The important bands in the IR spectra and the main 1H- and 13C-NMR signals are assigned and discussed in relation to molecular structure. The wavelengths of the principal electronic absorption peaks have been accounted for quantitatively in terms of crystal field theory and various parameters were evaluated. The complexes, [Ru(HL n )Cl3] n , are penta-coordinate; and, a trigonal-bipyramidal environment is commensurate for the Ru(III) ion. The presence of a coordinated water molecule in complex the Cu(II) complex (20) was demonstrated by thermogravimetry. The compounds, [N-(3-phenylacrylidene)-2-mercaptoaniline] (HL1) and cinnamaldehyde-2-aminophenol (HL2), act as monobasic and neutral bidentate ligands. The B-value suggests a strong covalency in the metal-ligand σ-bond. Tentative structures of the polymer complexes are proposed.

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REFERENCES

  1. F. M. Reicha, M. El-Hiti, A. Z. El-Sonbati, and M. A. Diab, J. Phys. D, Appl. Phys. 24, 369(1991).

    Google Scholar 

  2. A. Z. El-Sonbati and A. M. Hassanein, Polym. Deg. and Stab. 46, 31(1994).

    Google Scholar 

  3. A. Z. El-Sonbati and A. M. Hassanein, Polym, Deg. and Stab. 48, 35(1995).

    Google Scholar 

  4. A. Z. El-Sonbati, A. A. EI-Bindary, M. A. Diab, and S. A. Mazrouh, Monatsh. Chem. 124, 793(1993).

    Google Scholar 

  5. A. Z. Sonbati and A. M. Hassanein, Polym. Deg. and Stab. 48, 45(1995).

    Google Scholar 

  6. A. Z. El-Sonbati and M. A. Hefni, Monatsh. Chem. 124, 419(1993).

    Google Scholar 

  7. A. Z. El-Sonbati, A. A. El-Bindary, M. A. Diab, M. A. El-Ela, and S. A. Mazrouh, Polymer 35, 647(1994).

    Google Scholar 

  8. A. F. Shoair, A. A. El-Bindary, A. Z. El-Sonbati, and R. M. Younes, Polish J. Chem. 74, 1047(2000).

    Google Scholar 

  9. A. Z. EI-Sonbanti, A. A. El-Bindary, and I. G. Rashed, Spectrochim. Acta Part A 58, 1411(2002).

    Google Scholar 

  10. A. A. El-Bindary, A. S. Al-Shihri, and A. Z. El-Sonbati, Design. Monom. And Polym. 6, 283(2003).

    Google Scholar 

  11. A. Z. El-Sonbati, A. A. El-Bindary, and M. A. Diab, Spectrochim. Acta Part A 59, 443(2003).

    Google Scholar 

  12. A. A. El-Bindary, A. Z. El-Sonbati, and N. A. EI-Deeb, J. Appl. Polym. Sci. 77, 2552(2000).

    Google Scholar 

  13. R. M. Issa, A. Z. El-Sonbati, A. A. El-Bindary, and H. M. Kera, Eur. Polym. J. 39, 561(2002).

    Google Scholar 

  14. A. A. El-Bindary, Synth. React. Inorg. Met.-Org. Chem. 28, 1743(1998).

    Google Scholar 

  15. C. J. Thompson and D. H. Busch, J. Am. Chem. Soc. 86, 213(1964).

    Google Scholar 

  16. D. M. Grant and N. Grassie, J. Polym. Sci. 42, 587(1960).

    Google Scholar 

  17. J. S. Dwivedi and U. Agarwala, Indian J. Chem. 10, 657(1972).

    Google Scholar 

  18. P. W. Selwood, Magneto Chemistry (Interscience, New York, 1956).

    Google Scholar 

  19. R. G. Pearson, J. Am. Chem. Soc. 85, 3333(1963).

    Google Scholar 

  20. J. P. Day and L. M. Venanzi, J. Chem. Soc. (A) 1363(1966).

  21. S. P. McGlynn, J. K. Smith, and W. C. Nelly, J. Chem. Phys. 35, 105(1961).

    Google Scholar 

  22. L. H. Jones, Spectrochim. Acta 11, 409(1959).

    Google Scholar 

  23. S. P. McGlynn and J. K. S. Smith, J. Molec. Spectrosc. 6, 164(1961).

    Google Scholar 

  24. J. T. Bell, J. Inorg. Nucl. Chem. 31, 703(1969).

    Google Scholar 

  25. C. K. Jørgensen, Prog. Inorg. Chem. 4, 73(1962).

    Google Scholar 

  26. C. K. Jørgensen, Absorption Spectra and Chemical Bonding in Complexes (Pergamon Press, New York, 1964), p. 183.

    Google Scholar 

  27. C. K. Jørgensen, Acta Chim. Scand. 10, 5000(1956).

    Google Scholar 

  28. C. Preti and G. Tosi, Transition Met. Chem. 3, 17(1978).

    Google Scholar 

  29. R. S. Drago, Physical Methods in Chemistry (Saunders, Philadelphia, 1977).

    Google Scholar 

  30. P. Viswanathamurthi, N. Dharmaraj, S. Anuradha, and K. Natarajan, Transition Met. Chem. 23, 337(1998).

    Google Scholar 

  31. M. M. T. Khan, D. Srinivas, R. I. Kureshy, and N. H. Khan, Inorg. Chem. 29, 2320(1990).

    Google Scholar 

  32. H. B. Gray and C. J. Ballhansen, J. Am. Chem. Soc. 85, 260(1963).

    Google Scholar 

  33. A. A. El-Bindary and A. Z. El-Sonbati, Gazz. Chim. It. 127, 597(1997).

    Google Scholar 

  34. A. B. P. Lever, Inorganic Electronic Spectroscopy (Elsevier, Amsterdam, 1986).

    Google Scholar 

  35. B. N. Figgis, Introduction to Ligand Field (Wiley Eastern, New Delhi, 1976).

    Google Scholar 

  36. C. J. Ballahansen, Ligand Field Theory (McGraw–Hill, New York, 1962).

    Google Scholar 

  37. M. Ruiz, L. Perllo, R. Ortiz, A. Castineiras, C. Maichle Mossmer, and E. Canton, J. Inorg. Biochem. 59, 801(1995).

    Google Scholar 

  38. B. N. Figgis and J. Lewis, Progress in Inorganic Chemistry (Wiley-Interscience, New York, 1964), p. 37.

    Google Scholar 

  39. D. M. Adams, Metal-Ligand and Related Vibrations. Critical Survey of the Infrared and Raman Spectra of Metallic and Organometallic Compounds (Arnold, London, 1967).

    Google Scholar 

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science (Demiatta), Mansoura University, Demiatta, Egypt

    A. Z. El-Sonbati

  2. Chemistry Department, Faculty of Science, King Khalid University, Abha, Saudi Arabia

    A. S. Al-Shihri & A. A. El-Bindary

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  1. A. Z. El-Sonbati
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  2. A. S. Al-Shihri
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  3. A. A. El-Bindary
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Correspondence to A. Z. El-Sonbati.

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El-Sonbati, A.Z., Al-Shihri, A.S. & El-Bindary, A.A. Polymer Complexes XLV. Spectral Studies on Metal-Ligand Bonding in Novel Poly-Schiff Base Complexes. Journal of Inorganic and Organometallic Polymers 14, 53–71 (2004). https://doi.org/10.1023/B:JOIP.0000016754.30030.d7

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