Skip to main content
SpringerLink
Log in

Investigation of the Process of Hardening of Diglycidyl Ether Bisphenol a by Phosphate Binders

  • Published:
Journal of Engineering Physics and Thermophysics Aims and scope

Abstract

The interaction between diglycidyl ether bisphenol A and conventional and water‐deficient phosphate binders has been investigated. The data of chemical analysis, IR spectroscopy, and differential‐thermal analysis point to the formation of a spatially cross‐linked epoxy polymer under the influence of the phosphate binders. It has been shown that conventional binders can be used as high‐temperature hardeners of epoxy oligomers. When water‐deficient binders are used, the formation of a three‐dimensional polymer structure is observed at room temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. H. Lee and K. Nevill, Handbook of Epoxy Resins[Russian translation], Moscow (1973).

  2. M. I. Karyakina, Testing of Paint Materials and Coatings[in Russian], Moscow (1998).

  3. M. I. Finkel'shtein, Industrial Use of Epoxy-Based Paint Materials[in Russian], Leningrad (1983).

  4. L. N. Mashlyakovskii, A. D. Lykov, and V. Yu. Repkin, Organic Low-Inflammable Coatings[in Russian], Leningrad (1989).

  5. P. V. Nikolaev and L. N. Lebedeva, Phosphate hardeners - fire-retardants for environmentally full-valued epoxy-based paint materials, in: Ext. Abstr. of Papers presented at 1st All-Russia Conf. on Polymeric Materials of Low Inflammability[in Russian], Volgograd (1995), pp. 13-16.

  6. P. V. Nikolaev and L. N. Lebedeva, Influence of water and softeners on the technological properties and the process of hardening of epoxy oligomer ÉD-20, Zh. Prikl. Khim., 73, No. 1, 140-144 (2000).

    Google Scholar 

  7. M. F. Sorokin, Z. A. Kochnova, and P. V. Nikolaev, Study of reactions with the participation of water in epoxy-phenol compositions, Lakokrasochn. Mater. Primen., No. 6, 10-12 (1986).

    Google Scholar 

  8. V. A. Kopeikin, A. P. Petrova, and I. L. Rashkovan, Metallophosphate-Based Materials[in Russian], Moscow (1976).

  9. P. V. Nikolaev, A. V. Balashov, and V. A. Ignatov, Study of the compatibility of epoxy-phenol compositions with film-forming materials of magnetic varnish by the photocolorimetric method, Lakokrasochn. Mater. Primen., No. 6, 10-11 (1983).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National Academy of Sciences of Belarus, Institute of General and Inorganic Chemistry, 9 Surganov Str., Minsk, 220072, Belarus

    V. I. Dubkova, N. Kh. Belous & N. P. Krut'ko

  2. Development Establishment (DMSRDE) of the Ministry of Defense of the Government of India, Defense Materials & Stores Research &, Kanpur, India

    G. N. Matur & M. N. Saraf

Authors
  1. V. I. Dubkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. Kh. Belous
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. P. Krut'ko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. N. Matur
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. N. Saraf
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dubkova, V.I., Belous, N.K., Krut'ko, N.P. et al. Investigation of the Process of Hardening of Diglycidyl Ether Bisphenol a by Phosphate Binders. Journal of Engineering Physics and Thermophysics 76, 1334–1339 (2003). https://doi.org/10.1023/B:JOEP.0000012039.97874.fd

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JOEP.0000012039.97874.fd

Keywords

Search

Navigation