Skip to main content
SpringerLink
Log in

A Homoleptic Silver-Ferrocenylselenolate: Synthesis and Characterization of [Ag4(fcSe2)3]2−

  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

1,1′-Bis(trimethylsilylseleno)ferrocene has been used to synthesize the anionic cluster [Ag4(fcSe2)3]2− \(\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{2} \). In \(\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle-}$}}{2} \), a non-bonded tetrahedron of Ag atoms is stabilized by three bidentate ferrocenyldiselenolate groups, which bridge the edges of the tetrahedron in μ 2, μ 2 fashion. Multinuclear NMR spectroscopy indicates a static framework. Crystal data for [NBu4]2[Ag4(fcSe2)3]: monoclinic, P2(1)/n, a=19.8240(6), b=17.7514(5), c=21.1494(7) Å, β=111.88(3)°, V=6906.5(4) Å3.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. A. Togni and T. Hayashi (eds.), Ferrocenes: Homogeneous Catalysis, Organic Synthesis, Materials Science (VCH, Weinheim, 1994, 540 pp.

    Google Scholar 

  2. S.-W. A. Fong and T. S. A. Hor (1998). J. Cluster Sci. 9, 351.

    Google Scholar 

  3. R. Broussier, Y. Gobet, R. Amardeil, A. Da Rold, M. M. Kubicki, and B. Gautheron (1993). J. Organomet. Chem. 445, C4–C5.

    Google Scholar 

  4. S. Takemoto, S. Kuwata, Y. Nishibayashi, and M. Hidai (1998). Inorg. Chem. 37, 6428.

    Google Scholar 

  5. S. Dehnen, A. Eichhöfer, and D. Fenske (2002). Eur. J. Inorg. Chem. 279.

  6. I. Dance and K. Fisher (1994). Prog. Inorg. Chem. 41, 637.

    Google Scholar 

  7. J. Arnold (1995). Prog. Inorg. Chem. 43, 353.

    Google Scholar 

  8. V. W.-W. Yam, E. C.-C. Cheng, and N. Zhu (2002). New J. Chem. 26, 279.

    Google Scholar 

  9. C. Liu, X. Wang, Q. Gong, K. Tang, X. Jin, H. Yan, and P. Cui (2001). Adv. Mater. 13, 1687.

    Google Scholar 

  10. K. Tang, X. Jin, H. Yan, X. Xie, C. Liu, and Q. Gong (2001). Dalton Trans. 1374.

  11. V. W.-W. Yam (2001). Pure Appl. Chem. 73, 543.

    Google Scholar 

  12. V. W.-W. Yam, K. K.-W. Lo, C.-R. Wang, and K.-K. Cheung (1996). Inorg. Chem. 35, 5116.

    Google Scholar 

  13. C.-R. Wang, K. K.-W. Lo, and V. W.-W. Yam (1996). Chem. Phys. Lett. 262, 91.

    Google Scholar 

  14. C.-R. Wang, K. K.-W. Lo, and V. W.-W. Yam (1997). J. Chem. Soc., Dalton Trans. 227.

  15. V. W.-W. Yam (1997). J. Photochem. Photobio. A: Chem. 106, 75.

    Google Scholar 

  16. V. W.-W. Yam, K. K.-W. Lo, W. K.-M. Fung, and C.-R. Wang (1998). Coord. Chem. Rev. 171, 17.

    Google Scholar 

  17. V. W.-W. Yam, K.-L. Yu, E. C.-C. Cheng, P. K.-Y. Yeung, K.-K. Cheung, and N. Zhu (2002). Chem. Eur. J. 8, 4122.

    Google Scholar 

  18. P. J. Bonasia, G. P. Mitchell, F. J. Hollander, and J. Arnold (1994). Inorg. Chem. 33, 1797.

    Google Scholar 

  19. D. Fenske and T. Langetepe (2002). Angew. Chem. Int. Ed. 41, 300.

    Google Scholar 

  20. D. Fenske, N. Zhu, and T. Langetepe (1998). Angew. Chem. Int. Ed. 37, 2639.

    Google Scholar 

  21. C. C. McLauchlan and J. A. Ibers (2001). Inorg. Chem. 40, 1809.

    Google Scholar 

  22. A. Rodriguez, J. Romero, J. A. Garcia-Vazquez, M. L. Duran, A. Sousa-Pedrares, A. Sousa, and J. Zubieta (1999). Inorg. Chim. Acta 284, 133.

    Google Scholar 

  23. A. I. Wallbank and J. F. Corrigan (2001). Chem. Commun. 377.

  24. S. Canales, O. Crespo, A. Fortes, M. C. Gimeno, P. G. Jones, and A. Laguna (2002). Dalton Trans. 2250.

  25. D. Fenske and J. F. Corrigan, in P. Braunstein, L. A. Oro, and P. R. Raithby (eds.), Metal Clusters in Chemistry (Wiley-VCH, Weinheim, 1999), pp. 1302–1324.

    Google Scholar 

  26. J. Zhao, D. Adcock, and W. T. Pennington (1990). Inorg. Chem. 29, 4358.

    Google Scholar 

  27. X. Jin, K. Tang, Y. Long, Y. Liang, and Y. Tang (1999). Chem. J. Chin Uni. 20, 831.

    Google Scholar 

  28. G. Henkel, P. Betz, and B. Krebs (1987). Angew. Chem. Int. Ed. 26, 145.

    Google Scholar 

  29. G. Henkel, B. Krebs, P. Betz, H. Fietz, and K. Saatkamp (1988). Angew. Chem. Int. Ed. 27, 1326.

    Google Scholar 

  30. S. Canales, O. Crespo, M. C. Gimeno, P. G. Jones, A. Laguna, A. Silvestru, and C. Silvestru (2003). Inorg. Chim. Acta 347, 16.

    Google Scholar 

  31. S.-P. Huang and M. G. Kanatzidis (1991). Inorg. Chem. 30, 1455.

    Google Scholar 

  32. M. C. Gimeno and A. Laguna, in J. A. McCleverty and T. B. Meyer (eds.), Comprehensive Coordination Chemistry II (Elsevier Pergamon, Oxford, 2004), Vol. 6, Chap. 6.7.

    Google Scholar 

  33. P. Zanello, M. Casarin, L. Pardi, M. Herberhold, and G.-X. Jin (1995). J. Organomet. Chem. 503, 243.

    Google Scholar 

  34. T. P. Lebold, D. L. B. Stringle, M. S. Workentin, and J. F. Corrigan (2003). Chem. Commun. 1398.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, The University of Western Ontario, London, Ontario, N6A 5B7, Canada

    Andrew I. Wallbank & John F. Corrigan

Authors
  1. Andrew I. Wallbank
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. John F. Corrigan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to John F. Corrigan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wallbank, A.I., Corrigan, J.F. A Homoleptic Silver-Ferrocenylselenolate: Synthesis and Characterization of [Ag4(fcSe2)3]2− . Journal of Cluster Science 15, 225–232 (2004). https://doi.org/10.1023/B:JOCL.0000027404.10038.65

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JOCL.0000027404.10038.65

Search

Navigation