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Formation of Mixed Fe/W/S Complexes Bearing Oxo and Acetylide Ligands: Synthesis and Characterization of [(η 5-C5Me5)W2Fe2(CO)6(O)2(μ-O)(μ 3-S)2(η 1:η 2-CCR)] (R=Ph, (Me)C=CH2) and[(η 5-C5Me5)W2Fe2(CO)6(O)(μ-O)(μ 3-S)2(η 1:η 2-CCR)(η 2-RCCH)] (R=Ph, (Me)C=CH2)

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Abstract

Reaction of the acetylide-bearing oxo-peroxo complex [(η 5-C5Me5)W(O2)(O) (η 1-CCR)] (R=Ph, (Me)C=CH2) with [Fe2W(CO)10(μ 3-S)2] yielded [(η 5-C5Me5)W2Fe2(CO)6(O)2(μ-O)(μ 3-S)2(η 1:η 2-CCR)]. When the reaction was carried out in presence of free acetylene, RC≡CH (R=Ph, (Me)C=CH2), clusters [(η 5-C5Me5)W2Fe2(CO)6(O)(μ-O)(μ 3-S)2(η 1:η 2-CCR)(η 2-RCCH)] were obtained. Structures of one of each type of cluster were determined by single crystal X-ray diffraction methods.

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Authors and Affiliations

  1. Chemistry Department, Indian Institute of Technology, Powai, Bombay, 400076, India

    Pradeep Mathur & Anjan K. Bhunia

  2. National Single Crystal X-Ray Diffraction Facility, Indian Institute of Technology, Powai, Bombay, 400076, India

    Shaikh Md. Mobin

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  1. Pradeep Mathur
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Mathur, P., Bhunia, A.K. & Mobin, S.M. Formation of Mixed Fe/W/S Complexes Bearing Oxo and Acetylide Ligands: Synthesis and Characterization of [(η 5-C5Me5)W2Fe2(CO)6(O)2(μ-O)(μ 3-S)2(η 1:η 2-CCR)] (R=Ph, (Me)C=CH2) and[(η 5-C5Me5)W2Fe2(CO)6(O)(μ-O)(μ 3-S)2(η 1:η 2-CCR)(η 2-RCCH)] (R=Ph, (Me)C=CH2). Journal of Cluster Science 15, 175–187 (2004). https://doi.org/10.1023/B:JOCL.0000027401.20203.17

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