Skip to main content
SpringerLink
Log in

The Synthesis and Reactivity of New μ 2- and μ 3-Aminophosphinidene Cobalt Complexes

  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

The reaction of K[Co(CO)4] and PCl2(TMP) at −5°C leads to the unstable and reactive μ-phosphinidene complex [Co2(CO)6{μ-P(TMP)}] (1), while the same reaction carried out at 35°C gives the chlorophosphido and phosphinidene bridged cluster [Co3(CO)7{μ-P(Cl)TMP}{μ 3-P(TMP)}] (2) (TMP=2,2,6,6-tetramethylpiperidyl). Compound 1 reacts with dppm (dppm=bis(diphenyl- phosphino)methane) and [Co2(CO)8] to form the more stable substitution product [Co2(CO)4{μ-P(TMP)}(μ-dppm)] (3) and [Co4(CO)7(μ-CO)3{μ 3-P(TMP)}] (4) respectively. The first example of a cationic μ 3-phosphinidene cluster compound [Co3(CO)9{μ 3-P(TMP)}][AlCl4] (5) is obtained from reaction of 3 with AlCl3. The X-ray structures of clusters 2 and 5 are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. (a) A. W. Ehlers, E. J. Baerends, and K. Lammertsma (2002). J. Am. Chem. Soc. 124, 2831. (b) G. Frison, F. Mathey, and A. Sevin (1998). J. Organomet. Chem. 570, 225. (c) S. Creve, K. Pierloot, M. T. Nguyen, and L. G. Vanquickenborne (1999). Eur. J. Inorg. Chem. 107. (d) A. W. Ehlers, K. Lammertsma, and E. J. Baerends (1998). Organometallics 17, 2738.

    Google Scholar 

  2. (a) F. Mathey, N. H. Tran Huy, and A. Marinetti (2001). Helv. Chim. Acta 84, 2938. (b) K. Lammertsma and M. J. M. Vlaar (2002). Eur. J. Org. Chem. 1127. (c) S. Grigoleit, A. Alijah, A. B. Rozhenko, R. Streubel, and W. W. Scholler (2002). J. Organomet. Chem. 643/644, 223.

    Google Scholar 

  3. (a) A. H. Cowley (1997). Acc. Chem. Res. 30, 445. (b) T. L. Breen and D. W. Stephan (1995). J. Am. Chem. Soc. 117, 11914. (c) J. B. Bonnano, P. T. Wolczanski, and E. B. Loblovsky (1994). J. Am. Chem. Soc. 116, 11159.

    Google Scholar 

  4. (a) B. T. Sterenberg and A. J. Carty (2001). J. Organomet. Chem. 617, 696. (b) B. T. Sterenberg, K. A. Udachin, and A. J. Carty (2001). Organometallics 20, 2657. (c) J. Sánchez-Nieves, B. T. Sterenberg, K. A. Udachin, and A. J. Carty (2003). J. Am. Chem. Soc. 125, 2404. (d) B. T. Sterenberg, K. A. Udachin, and A. J. Carty (2003). Organometallics 22, 3927.

    Google Scholar 

  5. A. T. Termaten, T. Nijbacker, M. Schakel, M. Lutz, A. L. Spek, and K. Lammertsma (2003). Chem. Eur. J. 9, 2200.

    Google Scholar 

  6. (a) A. T. Termaten, H. Aktas, M. Schakel, A. W. Ehlers, M. Lutz, A. L. Spek, and K. Lammertsma (2003). Organometallics 22, 1827. (b) T. Termaten, T. Nijbacker, M. Schakel, M. Lutz, A. L. Spek, and K. Lammertsma (2002). Organometallics 21, 3196.

    Google Scholar 

  7. R. Melenkivitz, D. J. Mindiola, and G. L. Hillhouse (2002). J. Am. Chem. Soc. 124, 3846.

    Google Scholar 

  8. Z. Weng, W.-K. Leong, J. J. Vittal, and L.-Y. Goh (2003). Organometallics 22, 1657, and references therein.

    Google Scholar 

  9. (a) A. M. Arif, A. H. Cowley, N. C. Norman, A. G. Orpen, and M. Pakulski (1985). J. Chem. Soc., Chem. Commun. 1267. (b) A. M. Arif, A. H. Cowley, N. C. Norman, A. G. Orpen, and M. Pakulski (1988). Organometallics 7, 309. (c) I. V. Kourkine and D. S. Glueck (1997). Inorg. Chem. 36, 5160.

    Google Scholar 

  10. J. Sánchez-Nieves, B. T. Sterenberg, K. A. Udachin, and A. J. Carty (2003). Inorg. Chim. Acta 350, 486.

    Google Scholar 

  11. (a) G. Huttner and K. Knoll (1987). Angew. Chem. Int. Ed. Engl. 26, 743. (b) C. D. Housecroft, Inorganometallic Chemistry, T. P. Fehlner (ed.) (Plenum Press, New York, 1992), pp. 115-130.

    Google Scholar 

  12. (a) J. F. Corrigan, S. Doherty, N. J. Taylor, and A. J. Carty (1994). J. Am. Chem. Soc. 116, 9799. (b) W. Wang, J. F. Corrigan, S. Doherty, G. D. Enright, N. J. Taylor, and A. J. Carty (1996). Organometallics 15, 2770. (c) W. Wang and A. J. Carty (1997). New J. Chem. 21, 773. (d) J. H. Yamamoto, K. A. Udachin, G. D. Enright, and A. J. Carty (1998). Chem. Commun. 2259. (e) W. Wang, G. D. Enright, and A. J. Carty (1997). J. Am. Chem. Soc. 119, 12370. (f) W. Wang, G. D. Enright, J. Driediger, and A. J. Carty (1997). J. Organomet. Chem. 541, 461. (g) L. Scoles, J. H. Yamamoto, L. Brissieux, B. T. Sterenberg, K. A. Udachin, and A. J. Carty (2001). Inorg. Chem. 40, 6731. (h) J. H. Yamamoto, L. Scoles, K. A. Udachin, G. D. Enright, and A. J. Carty (2000). J. Organomet. Chem. 600, 84. (i) B. T. Sterenberg, L. Scoles, and A. J. Carty (2002). Coord. Chem. Rev. 231, 183.

    Google Scholar 

  13. (a) L. Markó and B. Markó (1975). Inorg. Chim. Acta. 14, L39. (b) R. B. King, W.-K. Fu, and E. M. Holt (1986). Inorg. Chem. 25, 2390.

    Google Scholar 

  14. J. Sánchez-Nieves, B. T. Sterenberg, K. A. Udachin, and A. J. Carty (2003). Can. J. Chem. 81, 1149.

    Google Scholar 

  15. H.-U. Reisacher, W. F. McNamara, E. N. Duesler, and R. T. Paine (1997). Organometallics 16, 449.

    Google Scholar 

  16. (a) H. Beurich, T. Madach, F. Richter, and H. Vahrenkamp (1979). Angew. Chem., Int. Ed. Engl. 18, 690. (b) R. C. Ryan and L. F. Dahl (1975). J. Am. Chem. Soc. 97, 6904. (c) R. C. Ryan, C. V. Pittman, and J. P. O'Connor (1980). J. Organomet. Chem. 193, 241. (d) A. M. Arif, A. H. Cowley, M. Pakulski, M. B. Hursthouse, and A. Karauloz (1985). Organometallics 4, 2227.

    Google Scholar 

  17. (a) M. E. Garcia, V. Riera, M. A. Ruiz, D. Saez, J. Vaissermann, and J. C. Jeffrey (2002). J. Am. Chem. Soc. 124, 14304. (b) M. E. Garcia, V. Riera, M. A. Ruiz, D. Saez, H. Hamidov, J. C. Jeffrey, and T. Riis-Johannessen (2003). J. Am. Chem. Soc. 125, 13044.

    Google Scholar 

  18. S. Onaka, H. Muto, Y. Katsukawa, and S. Takagi (1997). J. Organomet. Chem. 543, 241.

    Google Scholar 

  19. (a) J. S. Field, R. J. Haines, and F. Mulla (1990). J. Organomet. Chem. 389, 227. (b) J. S. Field, R. J. Haines, and F. Mulla (1992). J. Organomet. Chem. 439, C56.

    Google Scholar 

  20. U. Florke and H.-J. Haupt (1993). Z. Kristallogr. 204, 304.

    Google Scholar 

  21. V. Kumar, D. W. Lee, M. G. Newton, and R. B. King (1996). J. Organomet. Chem. 512, 1.

    Google Scholar 

  22. (a) K. Evertz and G. Huttner (1988). Chem. Ber. 121, 143. (b) R. L. De (1983). J. Organomet. Chem. 243, 331. (c) U. Florke and H.-J. Haupt (1996). Z. Kristallogr. 211, 333.

    Google Scholar 

  23. R. B. King and N. D. Sadanani (1985). Synth. React. Inorg. Met.-Org. Chem. 15, 149.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Steacie Institute for Molecular Sciences, National Research Council Canada, 100 Sussex Drive, Ottawa, Ont., Canada, K1A 0R6

    Javier Sánchez-Nieves, Brian T. Sterenberg, Konstantin A. Udachin & Arthur J. Carty

Authors
  1. Javier Sánchez-Nieves
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Brian T. Sterenberg
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Konstantin A. Udachin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Arthur J. Carty
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Arthur J. Carty.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sánchez-Nieves, J., Sterenberg, B.T., Udachin, K.A. et al. The Synthesis and Reactivity of New μ 2- and μ 3-Aminophosphinidene Cobalt Complexes. Journal of Cluster Science 15, 151–162 (2004). https://doi.org/10.1023/B:JOCL.0000027399.01179.fe

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JOCL.0000027399.01179.fe

Search

Navigation