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Syntheses and Crystal Structures of Some CCo3 Clusters Containing PPh3 or dppm Ligands

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Abstract

Molecular structural determinations are reported for six Co3C carbonyl cluster complexes containing tertiary phosphines, which have been isolated as by-products from a variety of reactions. Structural features are similar to those of related complexes already reported. Some discussion of apparent orientational preferences of the CH2 group of dppm ligands, which appear to enter into H-bonding interactions with amido or carboxylate substituents, is given. Appropriate comparisons are made with unsubstituted analogues.

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Authors and Affiliations

  1. Department of Chemistry, University of Adelaide, Adelaide, South Australia, 5005

    Michael I. Bruce, Kathy A. Kramarczuk, Gary J. Perkins & Natasha N. Zaitseva

  2. Department of Chemistry, University of Western Australia, Crawley, Western Australia, 6009

    Brian W. Skelton & Allan H. White

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  1. Michael I. Bruce
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  2. Kathy A. Kramarczuk
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  3. Gary J. Perkins
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  4. Brian W. Skelton
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  5. Allan H. White
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  6. Natasha N. Zaitseva
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Correspondence to Michael I. Bruce.

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Bruce, M.I., Kramarczuk, K.A., Perkins, G.J. et al. Syntheses and Crystal Structures of Some CCo3 Clusters Containing PPh3 or dppm Ligands. Journal of Cluster Science 15, 119–137 (2004). https://doi.org/10.1023/B:JOCL.0000027397.89365.42

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  • DOI: https://doi.org/10.1023/B:JOCL.0000027397.89365.42

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