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The Addition of Platinum and Palladium Groups to the Disulfido Ligand in Cyclopentadienyl Molybdenum-Manganese Carbonyl Complexes

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Abstract

The reaction of the complexes CpMoMn(CO)5(μ-S2), 2a, Cp=C5H5 and Cp*MoMn(CO)5(μ-S2), 2b, Cp*=C5Me5with (PPh3)2Pt(PhC2Ph) yielded the new bis-sulfido mixed metal complexes CpMoMn(CO)5Pt(PPh3)2(μ 3-S)2, 3a and Cp*MoMn(CO)5Pt(PPh3)2(μ 3-S)2, 3b by insertion of a platinum metal grouping into the S–S bond. A mono-phosphine complex, Cp*MoMn(CO)6Pt(PPh3)(μ 3-S)2, 4b was also isolated from the reaction of 2b with (PPh3)2Pt(PhC2Ph). Compounds 3b and 4b were both characterized crystallographically. Both complexes consist of open MoMnPt clusters with a Mo–Mn single bond, Mo–Mn=2.7570(16) Å for 3b and Mo–Mn=2.7837(13) Å for 4b, and two triply bridging sulfido ligands. The trimetallic complexes CpMo(O)MnPd(PBut 3)(CO)5(μ 3-S), 5a and Cp*Mo(O)MnPd(PBut 3)(CO)5(μ 3-S), 5b containing an oxo ligand bonded to molybdenum were obtained from the reaction of 2a–b with Pd(PBut 3)2. The molecular structure of the 5a was also established crystallographically.

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  1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina, 29208

    Richard D. Adams & O-Sung Kwon

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  1. Richard D. Adams
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  2. O-Sung Kwon
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Correspondence to Richard D. Adams.

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Adams, R.D., Kwon, OS. The Addition of Platinum and Palladium Groups to the Disulfido Ligand in Cyclopentadienyl Molybdenum-Manganese Carbonyl Complexes. Journal of Cluster Science 14, 367–379 (2003). https://doi.org/10.1023/B:JOCL.0000005069.59971.39

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  • DOI: https://doi.org/10.1023/B:JOCL.0000005069.59971.39

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