Skip to main content
SpringerLink
Log in

Synthesis and crystal structure of [{V3(μ-Cl)4(μ 3-Cl) (μ 3-OH)(thf)2(teeda)}2]·2(thf) (teeda = N,N,N′N′-tetraethylethane-1,2-diamine)

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The title complex was prepared from the reaction of [V2(μ-Cl)3(thf)3]2[Zn2Cl6] with N,N,N′N′-tetraethylethane-1,2-diamine (teeda) in refluxing thf and its crystal structure exhibits two triangulo-[V3(μ-Cl)3(μ-Cl)(μ 3-OH)(thf)2(teeda)]+ cations bridged by two chlorides. The molecular structure (monoclinic, space group P2 1/n, Z = 2, a = 11.8005(7) Å, b = 18.7492(14) Å, c= 15.6253(9) Å, β = 103.600(4) shows each vanadium site in a distorted octahedral geometry. V1 and V2 have two thf molecules bounded in cis configuration, and V3 completes the hexa-coordination with the diamine teeda. Main bond distances are 2.5149(12) Å for V(1)-μ-Cl(1), 2.062(3) Å for V(1)-μ 3-O(3), 2.5554(12) Å for V(1)-μ 3-Cl(4), 2.140(3) Å for V(1)–O(1)(thf), 2.243(4) Å for V(3)–N(1)(teeda), and 3.0437(9) for V(1)···V(2).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Luneva, N.P.; Moravsky, A.P.; Shilov, A.E. Nouv. J. Chim. 1982, 6, 245.

    Google Scholar 

  2. Shilov, A.E. J. Mol. Catal. A: Chem. 1987, 41, 221.

    Google Scholar 

  3. Einsle, O.; Tezcan, F.A.; Andrade, S.L.A.; Schmid, B.; Yoshida, M.; Howard, J.B.; Rees, D.C. Science 2002, 297, 1696.

    Google Scholar 

  4. Smith, B.E. Science 2002, 297, 1654.

    Google Scholar 

  5. Rehder, D. J. Inorg. Biochem. 2000, 80, 133.

    Google Scholar 

  6. Eady, R.R.; Leigh, G.J. J. Chem. Soc., Dalton Trans. 1994, 2739.

  7. Robson, R.L.; Eady, R.R.; Richardson, T.H.; Miller, R.W.; Hawkins, M.; Postgate, J.R. Nature (London) 1986, 322, 388.

    Google Scholar 

  8. Nunes, F.S.; Raimondi, A.C.; Niedwieski, A.C.; Quim. Nova 2003, 26, 872.

    Google Scholar 

  9. Fryzuk, M.D.; Johnson, S.A. Coord. Chem. Rev. 2000, 200, 379.

    Google Scholar 

  10. Leigh, G.J. Science 1998, 279, 506.

    Google Scholar 

  11. Bazhenova, T.A.; Shilov, A.E. Coord. Chem. Rev. 1995, 144, 69.

    Google Scholar 

  12. Edema, J.J.H.; Stauthamer, W.; van Bolhuis, F.; Gambarotta, S.; Smeets, W.J.J.; Spek, A.L. Inorg. Chem. 1990, 29, 1302.

    Google Scholar 

  13. Hitchcock, P.B.; Hughes, D.L.; Larkworthy, L.F.; Leigh, G.J.; Marmion, C.J.; Sanders, J.R.; Smith, G.J.; de Souza, J.S. J. Chem. Soc., Dalton Trans. 1997, 1127.

  14. Niedwieski, A.C.; Hitchcock, P.B.; da Motta, J.D.; Wypych, F.; Leigh, G.J.; Nunes, F.S. J. Braz. Chem. Soc. 2003, 14, 750.

    Google Scholar 

  15. Perrin, D.D.; Armarego, W.L.F. Purification of Laboratory Chemicals; Butterworth Heenemann: Oxford, 1997; 3rd ed., pp. 145 and 284.

    Google Scholar 

  16. Bouma, R.J.; Teuben, J.H.; Beukema, W.R.; Bansemer, R.L.; Huffman, J.C.; Caulton, K.G. Inorg. Chem. 1984, 23, 2715.

    Google Scholar 

  17. Sheldrich, G.M. SHELXL97, Program for Crystal Structure Refinement; University of Göttingen, Germany: 1997.

    Google Scholar 

  18. Farrugia, L.J. J. Appl. Cryst. 1997, 30, 565.

    Google Scholar 

  19. Farrugia, L.J. J. Appl. Cryst. 1999, 32, 837.

    Google Scholar 

  20. Blessing, C.F.R.H. Acta Cryst. 1995, A51, 33.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento de Química, Universidade Federal do Paraná, Centro Politécnico C. P. 19081, 81531-990, Curitiba, PR, Brazil

    Antonio Carlos Niedwieski & Fábio Souza Nunes

  2. Henry Taube Institute, P.O. 19585, Stanford, CA, 94309, USA

    Tai Hasegawa

Authors
  1. Antonio Carlos Niedwieski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tai Hasegawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Fábio Souza Nunes
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Niedwieski, A.C., Hasegawa, T. & Nunes, F.S. Synthesis and crystal structure of [{V3(μ-Cl)4(μ 3-Cl) (μ 3-OH)(thf)2(teeda)}2]·2(thf) (teeda = N,N,N′N′-tetraethylethane-1,2-diamine). Journal of Chemical Crystallography 34, 529–532 (2004). https://doi.org/10.1023/B:JOCC.0000042021.64468.8c

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JOCC.0000042021.64468.8c

Search

Navigation