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Synthesis and structure of a novel one-dimensional chain compound formed by copper(II) and nitronyl nitroxide radical

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Abstract

A novel compound formed by copper(II) and a carboxy-substituted nitronyl nitroxide of formula [Cu2(NITpBAH)2Cl4] (NITpBAH = [2-(4′-carboxy-phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-3-oxide]) has been synthesized. The compound crystallizes in the monoclinic space group P21/c with a = 9.5464(10), b = 12.4501(12), c = 14.3627(14) Å, β = 95.200(2)°, and Z = 2. X-ray analysis reveals [Cu2(NITpBAH)2Cl4] units to be linked into infinite chains by radical bridging ligands with N\( - -\)O of nitronyl nitroxide and substituted carboxy; there are the weak hydrogen bond interactions between chains.

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071, people's Republic of China

    Qi-Hua Zhao, Zong-Hui Jiang, Dai-Zheng Liao & Shi-Ping Yan

  2. Department of Chemistry, Yunnan University, Kunming, People's Republic of China

    Qi-Hua Zhao & Rui-Bin Fang

  3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, People's Republic of China

    Li-Cun Li

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  1. Qi-Hua Zhao
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  2. Li-Cun Li
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Zhao, QH., Li, LC., Jiang, ZH. et al. Synthesis and structure of a novel one-dimensional chain compound formed by copper(II) and nitronyl nitroxide radical. Journal of Chemical Crystallography 34, 191–194 (2004). https://doi.org/10.1023/B:JOCC.0000021563.00957.85

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