Skip to main content
SpringerLink
Log in

Synthesis and electrochemical properties of Indium doped spinel LiMn2O4

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this paper, spinel LiMn2−x In x O4 powder were prepared by rheological phase reaction method with the CH3COOLi·2H2O, (CH3CO2)2Mn·4H2O, and In2O3. The structures were characterized by X-ray diffraction and the electrochemical cycling performance were also observed. The results showed that the spinel LiMn2−x In x O4 were pure phase with very excellent performance. As a cathode material for lithium secondary batteries, LiMn1.98In2O4 had a high initial discharge-capacity with 132.42 mAh/g and a good cyclic reversibility with 98.9%. Even after 60 cycles, the discharge capacity still kept 126.29 mAh/g.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Ohzuka, M. Kitagawa and T. Hirai, J. Electrochem. Soc. 137 (1990) 769.

    Google Scholar 

  2. J. M. Tarascon, E. Wang, F. K. Shokoohi, W. R. Mckinnon and S. Colson, ibid. 138 (1991) 2859.

    Google Scholar 

  3. Y. K. Sun and H. Jin, J. Mater. Chem. 8 (1998) 2399.

    Google Scholar 

  4. K.-T. H. Wang, W.-S. Um, H. S. Lee, J. K. Song and K.-W. Chung, J. Power Sour. 74 (1998) 169.

    Google Scholar 

  5. C. H. Jung, J. Y. Park, S. T. Oh and H. K. Park, J. Nuclear Mater. 253 (1998) 203.

    Google Scholar 

  6. M. M. Thackeray, J. Electrochem. Soc. 142 (1995) 2558.

    Google Scholar 

  7. M. M. Thackeray, J. Solid State Chem. 132 (1997) 127.

    Google Scholar 

  8. K. Amine, H. Tukamoto, H. Yasuda and Y. Fujita, J. Electrochem. Soc. 143 (1996) 1607.

    Google Scholar 

  9. Q. Zhong, A. Bonakdarlpour, M. Zhang, Y. Gao and J. K. Dahn, ibid. 144 (1997) 205.

    Google Scholar 

  10. R. Bittihn, R. Herr and D. Hoge, J. Power Sour. 43 (1993) 223.

    Google Scholar 

  11. T. Ohzuku, S. Takeda and M. M. Iwanage, ibid. 81 (1999) 90.

    Google Scholar 

  12. P. Barbonux, J. M. Tarascon and F. K. Shokoohi, J. Solid State Chem. 94 (1991) 185.

    Google Scholar 

  13. M. Y. Saïdi, J. Barker and R. Koksbang, Electrochim. Acta. 41 (1996) 199.

    Google Scholar 

  14. H.-J. Choi, K.-M. Lee and J.-G. Lee, J. Power Sour. 103 (2001) 154.

    Google Scholar 

  15. A. De Kock, E. Ferg and R. J. Gumnow, ibid. 70 (1998) 247.

    Google Scholar 

  16. M. Okada, Y.-S. Lee and M. Yoshio, ibid. 90 (2000) 196.

    Google Scholar 

  17. R. J. Gummow, A. De Kock and M. M. Thackeray, Solid State Ionics 69 (1994) 59.

    Google Scholar 

  18. Y. Zhang, K. L. Zhang, M. K. Jia, H. Tang, J. T. Sun and L. J. Yuan, Chem. Lett. 2 (2002) 176.

    Google Scholar 

  19. H. Tang, C. Q. Feng, Q. Fan, T. M. Lei, J. T. Sun, L. J. Yuan and K. L. Zhang, ibid. 8 (2002) 822.

    Google Scholar 

  20. N. Hayashi, H. Ikuta and M. Wakihara, J. Electrochem. Soc. 146 (1999) 1351.

    Google Scholar 

  21. K.-J. Hong and Y.-K. Sun, J. Power Sour. 109 (2002) 427.

    Google Scholar 

  22. L. Guohua, H. Ikuta, T. T. Uchida and M. Wakihara, J. Electrochem. Soc. 14 (1996) 17.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, People's Republic of China

    H. W. Liu, C. Q. Feng, H. Tang, L. Song & K. L. Zhang

Authors
  1. H. W. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Q. Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Tang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. K. L. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liu, H.W., Feng, C.Q., Tang, H. et al. Synthesis and electrochemical properties of Indium doped spinel LiMn2O4 . Journal of Materials Science: Materials in Electronics 15, 495–497 (2004). https://doi.org/10.1023/B:JMSE.0000032582.22692.af

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JMSE.0000032582.22692.af

Keywords

Search

Navigation