Abstract
This paper reviews recent research upon the application of Raman microscopy to the characterisation of silicon carbide monofilaments produced by CVD (chemical vapour deposition). It is demonstrated that Raman microscopy is an invaluable technique allowing qualitative information about stoichoimetry variation in silicon carbide monofilaments to be obtained, as it readily detects both crystalline and amorphous carbon and silicon. It is shown that it is possible to characterise the morphology of the SiC crystallites in the monofilaments from analysis of the Raman line shapes. It is also demonstrated that Raman spectroscopy can be used to follow deformation of SiC monofilaments and to determine residual stresses in SiC-monofilament-reinforced metal-matrix composites. In addition, it is shown that it is possible to evaluate internal stresses in the carbon coatings of SiC monofilaments.
Similar content being viewed by others
References
P. MARTINEAU, M. LAHAYE, R. PAILLER, R. NASLAIN, M. COUZI and F. CRUEGE, J. Mater. Sci. 19 (1984) 2731.
D. W. FELDMAN, J. H. PARKER, JR, W. J. CHOYKE and L. PATRICK, Phys. Rev. 170 (1968) 698.
Idem., ibid. 173 (1968) 787.
S. NAKASHIMA and H. HARIMA, Phys. Stat. Sol. (a) 162 (1997) 39.
Y. SASAKI, Y. NISHINA, M. SATO and K. OKAMURA, Phys. Rev. 40 (1989) 1762.
J. F. DIGREGORIO and T. E. FURTAK, J. Amer. Ceram. Soc. 75 (1192) 1854.
Y. SASAKI, Y. NISHINA, M. SATO and K. OKAMURA, J. Mater. Sci. 22 (1987) 443.
R. J. DAY, V. PIDDOCK, R. TAYLOR, R. J. YOUNG and M. ZAKIKHANI, ibid. 24 (1989) 2898.
S. KARLIN and PH. COLOMBAN, J. Raman Spectr. 28 (1997)
R. T. BHATT and D. R. HULL, Ceram. Engng. Sci. Proc. 12 (1991) 1832.
E. ANASTASSAKIS, A. PINCZUK and E. BURSTEIN, Solid State Commun. 8 (1970) 133.
D. OLEGO, M. CARDONA and P. VOGEL, Phys. Rev. B 25 (1982) 3878.
J. F. DIGREGORIO, T. E. FURTAK and J. J. PETROVIC, J. Appl. Phys. 71 (1992) 3524.
N. MELANITIS and G. GALIOTIS, J. Mater. Sci. 25 (1990) 5081.
Y. HUANG and R. J. YOUNG, Carbon 33 (1995) 97.
X. YANG and R. J. YOUNG, Brit. Ceram. J. 93 (1994) 1.
G. GOUADEC, S. KARLIN and P h. COLOMBAN, Compos-ites B 29 (1998) 251.
R. J. YOUNG. A. BROADBRIDGE and S. L. SO, J. Microscopy 196 (1999) 257.
H. HARIMA, S. NAKASHIMA and T. UEMURA, J. Appl. Phys. 78 (1995) 1996.
P. J. COLWELL and M. V. KLEIN, Phys. Rev. 6 (1972) 498.
Y. WARD and R. J. YOUNG, (unpublished results).
H. RICHTER, Z. P. WANGand L. LEY, Solid State Commun. 39 (1981) 625.
T. TANAKA, E. MARUYAMA, T. SHIMADA and H. OKAMOTO,"Amorphous Silicon" (John Wiley & Sons Ltd., Chichester, 1999) p. 78.
Z. IQBAL, S. VEPREK, A. P. WEBB and P. CAPEZZUTO, Solid State Commun. 37 (1981) 993.
F. TUINSTRA and J. L. KOENIG, J. Chem. Phys. 53 (1970) 1126.
C. CHIEN, G. DRESSELHAUS and M. ENDO, Phys. Rev.B 26 (1982) 5867.
N. H. CHO, K. M. KRISHNAN, D. K. VEIRS, M. D. RUBIN, C. B. HOPPER, B. BHUSHAN and D. B. BOGY, J. Mater. Res. 5 (1990) 2543.
D. S. KNIGHT and W. B. WHITE, ibid. 4 (1989) 385.
A. C. FERRARI and J. ROBERTSON, Phys. Rev.B61 (2000) 14095.
Idem., ibid. B 65 (2001) 1762.
I. POCSIK, M. HUNDHAUSEN, M. KOOS and L. LEY, J. Non. Cryst. Solids. 227-230 (1998) 1083.
J. KIM, S. TLALI, H. E. JACKSON, J. E. WEBB and R. N. SINGH, J. Appl. Phys. 82 (1997) 407.
Y. WARD, R. J. YOUNG and R. SHATWELL, J. Mater. Sci. 36 (2001) 55.
M. H. BRODSKY and M. CARDONA, J. Non. Cryst. Solids. 31 (1978) 81.
T. KRAFT, K. G. NICKEL and Y. G. GOGOTSI, J. Mater. Sci. 33 (1998) 4357.
X. J. NING, P. PIROUZ and S. C. FARMER, J. Amer. Ceram. Soc. 76 (1993) 2033.
X. J. NING and P. PIROUZ, J. Mater. Res. 6 (1991) 2234.
T. C. DAMEN, S. P. S. PORTO and B. TELL, Phys. Rev. 142 (1966) 570.
T. T. CHENG, I. P. JONES, R. A. SHATWELL and P. DOORBAR, Mater. Sci. Eng. A 260 (1999) 139.
S. NAKASHIMA, H. OHTA, M. HANGYO and B. BALOSZ, Philos. Mag. B 70 (1994) 971.
R. SHATWELL, K. L. DYOS, C. PRENTICE, Y. WARD and R. J. YOUNG, J. Microscopy 201 (2001)
K. K. TIONG, P. M. AMIRTHARAJ and F. H. POLLAK, Appl. Phys. Lett. 44 (1984) 122.
S. ROHMFELD, M. HUNDHAUSENand L. LEY, Phys. Rev. 58 (1998) 9858.
Y. WARD, R. J. YOUNG and R. A SHATWELL, Composites A 33 (2002) 1409.
C. M. WARWICK and T. W. CLYNE, J. Mater. Sci. 26 (1991) 3817.
H. L. COX, Brit. J. Appl. Phys. 3 (1952) 72.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ward, Y., Young, R.J. & Shatwell, R.A. Application of Raman microscopy to the analysis of silicon carbide monofilaments. Journal of Materials Science 39, 6781–6790 (2004). https://doi.org/10.1023/B:JMSC.0000045606.60263.27
Issue Date:
DOI: https://doi.org/10.1023/B:JMSC.0000045606.60263.27