Skip to main content
SpringerLink
Log in

Linear viscoelasticity of semiconducting polyaniline based electrorheological suspensions

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

A dry-base electrorheological (ER) fluid was prepared by dispersing synthesized semiconducting polyaniline (PANI) particles into silicone oil, and its viscoelastic properties were investigated under applied electric fields using a rotational rheometer. Within the linear viscoelastic region, the ER fluid was observed to be elastic, due to columnar structure of PANI particles sustaining the deformation. Its rheological functions (G′ and G″) were interpreted based on the dimensional analysis, and they showed roughly linear electric-field dependence of the dimensional collapse of the viscoelastic behavior with frequency suggesting that the interactions between highly irregular particles are saturating even at these relatively low values of the dielectric mismatch. Furthermore, the recovery percentage obtained from the creep and recovery experiments increased with applied electric fields.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. X. P. Zhao and J. B. Yin, Chem. Mater. 14 (2002) 2258.

    Google Scholar 

  2. J. H. Park and O. O. Park, Korea-Australia Rheol. J. 13 (2001) 13.

    Google Scholar 

  3. Y. An, B. Liu and M. T. Shaw, Int. J. Mod. Phys. B 16 (2002) 2440.

    Google Scholar 

  4. T. C. Halsey and W. Toor, Phys. Rev. Lett. 65 (1990) 2820.

    Google Scholar 

  5. J. W. Kim, H. J. Choi, H. G. Lee and S. B. Choi, J. Ind. Eng. Chem. 7 (2001) 218.

    Google Scholar 

  6. M. Parthsarathy, K. H. Ahn, B. Belongia and D. J. Klingenberg, Int. J. Mod. Phys. B 8 (1994) 2789.

    Google Scholar 

  7. D. Jeon, C. Park and K. Park, ibid. B 13 (1999) 2221.

    Google Scholar 

  8. M. S. Cho, H. J. Choi, I. J. Chin and W. S. Ahn, Micropor. Mesopor. Mater. 32 (1999) 233.

    Google Scholar 

  9. J. E. Martin, D. Adof and T. C. Halsey, J. Colloid Interf. Sci. 167 (1994) 437.

    Google Scholar 

  10. D. R. Gamota and F. E. Filisko, J. Rheol. 35 (1991) 1411.

    Google Scholar 

  11. T. C. B. Mcleish, T. Jordan and M. T. Shaw, ibid. 35 (1991) 427.

    Google Scholar 

  12. G. B. Thurston and E. B. Gaertner, ibid. 35 (1991) 1327.

    Google Scholar 

  13. M. S. Cho, Y. J. Choi, H. J. Choi, S. G. Kim and M. S. Jhon, J. Molecular Liq. 75 (1998) 13.

    Google Scholar 

  14. S. H. Chu, S. J. Lee and K. H. Ahn, J. Rheol. 44 (2000) 105.

    Google Scholar 

  15. H. J. Choi, M. S. Cho, K. K. Kang and W. S. Ahn, Micropor. Mesopor. Mater. 39 (2000) 19.

    Google Scholar 

  16. Y. D. Kim and D. J. Klingeberg, J. Colloid Interf. Sci. 183 (1996) 568.

    Google Scholar 

  17. S. Wu, F. Zeng and J. Shen, J. Appl. Polym. Sci. 67 (1998) 2077.

    Google Scholar 

  18. H. BÖse, Int. J. Mod. Phys. B 13 (1999) 1878.

    Google Scholar 

  19. H. Block and J. P. Kelly, J. Phys. D: Appl. Phys. 21 (1988) 1661.

    Google Scholar 

  20. H. J. Choi, T. W. Kim, M. S. Cho, S. G. Kim and M. S. Jhon, Eur. Polym. J. 33 (1997) 699.

    Google Scholar 

  21. X. P Zhao and X. Duan, Int. J. Modern Phys. B 16 (2002) 2454.

    Google Scholar 

  22. A. Lengalova, V. Pavlinek, P. Saha, J. Stejskal, T. Kitano and O. Quadrat, Physica A 321 (2003) 411.

    Google Scholar 

  23. H. J. Choi, M. S. Cho and K. To, ibid. A 254 (1998) 272.

    Google Scholar 

  24. H. J. Choi, J. W. Kim and K. To, Synth. Met. 101 (1999) 697.

    Google Scholar 

  25. J. Trlica, P. SÁha, O. Quadrat and J. Stejskal, Eur. Polym. J. 36 (2000) 2313.

    Google Scholar 

  26. B. D. Chin, Y. S. Lee and O. O. Park, Int. J. Mod. Phys. B 13 (1999) 1852.

    Google Scholar 

  27. I. S. Sim, J. W. Kim, H. J. Choi, C. A. Kim and M. S. Jhon, Chem. Mater. 13 (2001) 1243.

    Google Scholar 

  28. J. W. Goodwin, G. M. Markham and B. Vinent, J. Phys. Chem. B 101 (1997) 1961.

    Google Scholar 

  29. J. W. Kim, F. Liu, H. J. Choi, S. H. Hong and J. Joo, Polymer 44 (2003) 289.

    Google Scholar 

  30. J. I. Sohn, M. S. Cho, H. J. Choi, C. A. Kim and M. S. Jhon, Macromol. Chem. Phys. 203 (2002) 1135.

    Google Scholar 

  31. R. Sakurai, H. See, T. Saito, S. Asai and M. Sumita, Rheol. Acta 38 (1999) 478.

    Google Scholar 

  32. H. J. Choi, J. W. Kim, S. H. Yoon, R. Fujiura, M. Komatsu and M. S. Jhon, J. Mater. Sci. Lett. 18 (1999) 1445.

    Google Scholar 

  33. S. G. Kim, H. J. Choi and M. S. Jhon, Macromol. Chem. Phys. 202 (2001) 521.

    Google Scholar 

  34. S. G. Kim, J. W. Kim, W. H. Jang, H. J. Choi and M. S. Jhon, Polymer 42 (2001) 5005.

    Google Scholar 

  35. J. Trlica, P. SÁha, O. Quadrat and J. Stejskal, J. Phys. D: Appl. Phys. 33 (1999) 1773.

    Google Scholar 

  36. Y. H. Cho, M. S. Cho, H. J. Choi and M. S. Jhon, Colloid Polym. Sci. 280 (2002) 1062.

    Google Scholar 

  37. Y. H. Lee, C. A. Kim, W. H. Jang, H. J. Choi and M. S. Jhon, Polymer 42 (2001) 8277.

    Google Scholar 

  38. J. W. Kim, M. H. Noh, H. J. Choi, D. C. Lee and M. S. Jhon, ibid. 41 (2000) 1229.

    Google Scholar 

  39. J. W. Kim, S. G. Kim, H. J. Choi and M. S. Jhon, Macromol. Rapid Commun. 20 (1999) 450.

    Google Scholar 

  40. J. W. Kim, F. Liu and H. J. Choi, J. Ind. Eng. Chem. 8 (2002) 399.

    Google Scholar 

  41. J. Joo, S. M. Long, J. P. Pouget, E. J. Oh, A. G. Macdiamid and A. J. Epstein, Phys. Rev. B 57 (1998) 9567.

    Google Scholar 

  42. J. Steskal, T. Sulimenko, J. ProkeŠ and I. Sapurina, Colloid Polym. Sci. 278 (2000) 654.

    Google Scholar 

  43. O. Quadrat, J. Stejskal, P. KratochvÍl, C. Klason, D. Mcqueen, J. KubÁt and P. SÁha, Synth. Met. 97 (1998) 37.

    Google Scholar 

  44. M. Leclerc, J. Guay and L. H. Dao, Macromolecules 22 (1989) 649.

    Google Scholar 

  45. K. Koyama, K. Minagawa, T. Yoshida and N. Kuramoto, Mod. Phys. Lett. 8 (1994) 1563.

    Google Scholar 

  46. M. Parthasarathy and D. Klingenberg, Rheol. Acta. 34 (1995) 430.

    Google Scholar 

  47. H. J. Choi, M. S. Cho, J. W. Kim, C. A. Kim and M. S. Jhon, Appl. Phys. Lett. 78 (2001) 3806.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Polymer Science and Engineering, Inha University, Incheon, 402-751, Korea

    M. S. Cho, J. H. Lee & H. J. Choi

  2. School of Chemical Engineering, Seoul National University, Seoul, 151-742, Korea

    K. H. Ahn & S. J. Lee

  3. Department of Mechanical Engineering, Sogang University, Seoul, 121-742, Korea

    D. Jeon

Authors
  1. M. S. Cho
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. H. Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. J. Choi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. H. Ahn
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. J. Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. D. Jeon
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cho, M.S., Lee, J.H., Choi, H.J. et al. Linear viscoelasticity of semiconducting polyaniline based electrorheological suspensions. Journal of Materials Science 39, 1377–1382 (2004). https://doi.org/10.1023/B:JMSC.0000013900.26175.cc

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JMSC.0000013900.26175.cc

Keywords

Search

Navigation