Abstract
New sulphides of transition metal ions [M+n = Cu+1, Cu+2 and Zn+2] have been synthesised in sunlight. XRD patterns show that these compounds are not MxSy but are mercaptyl, hydroxyl metal sulphides [M(SH)(OH)(H2O)2] which is further ascertained by I.R. spectra showing bands due to T d-symmetry. ESCA of compound of copper in solid state shows presence of Cu1+ and Cu2+ ion. The presence of hydroxyl, mercaptyl, aqua and S−2 groups has finally been confirmed with TGA, DTA and ESCA. Conductivity and Seebeck coefficient measurements show that compound of copper is p-type semiconductor and compound of zinc is n-type semiconductor. The production of these low cost materials opens an interesting area of research and development for their use in solar cell devices.
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References
N. N. Greenwood and A. Earnshaw, “Chemistry of the Element” (Pergamon Press, New York, 1989) p. 789, 795.
T. Ramasami and A. G. Ssykes, Inorg. Chem. 15 (1976) 1010.
M. Bilgin, J. Solid State Chem. (85) (1990) 283.
A. M. Femandez, P. S. Sebertion, J. Compos, Ogomz Daza and P. K. Nair, Thin Solid Film (Switzerland) 2327 (1994) 141.
R. A. Nayavist and R. O. Kagel, Infra Red, Spectra of Inorganic Compounds 3800-45 cm-1 (Academic Press, New York, 1971) p. 302, 225.
In ASTM card N.B.S. Circular 539 IV, 15-16 (1955).
J. P. Mishra and Lakshmi, J. Solid State Chem. 45 (1982) 381.
K. Nakamoto, J. Fugita and Kabayashi, J. Amer. Chem. Soc. 74 (1957) 4904.
Lakshmi, A. Sahay and S. Shukla, Ind. J. Chem. 1A (2001) 95.
D. M. Adams and E. Ernold, Metal-Ligand and Related Vibrations, London (1966).
A. Ardon and H. Taube, J. Amm. Chem. Soc. 8 (1967) 3661.
B. C. Bloodworth and R. Grazescowiak, Trans. Metal Chem. 4 (1979) 187.
I. Nakoi, T. Sugitani, K. Nagashima and Y. Niwa, J. Inorg. Nucl. Chem. 40 (1978) 789.
J. E. Huheey, E. A. Keiter and R. L. Keiter, “Inorganic Chem. Princ. Struct. React.,” 4th edn. (Harper Collins, 1993) p. 70.
C. A. Jacobson, “Encyclopedia Chemical Reaction” (Reinold Pub. Cor., New York, 1958).
Y. K. Ksendzov and I.-A. Drabkin, Sov. Phys. Solid State 7 (1965) 1579.
Lakshmi and U. C. Agarwal, J. Inorg. Nucl. Chem. 42 (1980) 450.
R. A. Rai, U. C. Agarwala and Lakshmi, Indian J. Chem. 18A (1979) 426.
R. Das, K. K. Nanda, A. K. Mukherjee, M. Mukherjee, M. Heliwell and K. Nag, J. Chem. Soc. Dalton Trans. (1993) 2241.
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Lakshmi, S., Sahay, A. & Shukla, S. Synthesis of new sulphides of transition metal ions in presence of sun light. Journal of Materials Science 39, 1325–1329 (2004). https://doi.org/10.1023/B:JMSC.0000013892.64323.34
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DOI: https://doi.org/10.1023/B:JMSC.0000013892.64323.34