Abstract
The synthesis of heteroditopic macrocyclic ureido-receptors is described. NMR studies show the formation of self-organized oligomeric superstructures. Membrane transport experiments show a direct relation between the self-assembling and the transport properties of these molecular information transfer devices. The self-organization of these receptors may provide the first evidence for the possible hybrid transport carrier versus channel mechanisms in liquid membranes.
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Barboiu, M. Supramolecular Polymeric Macrocyclic Receptors – Hybrid Carrier versus Channel Transporters in Bulk Liquid Membranes. Journal of Inclusion Phenomena 49, 133–137 (2004). https://doi.org/10.1023/B:JIPH.0000031126.58442.f4
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DOI: https://doi.org/10.1023/B:JIPH.0000031126.58442.f4