Abstract
The crystal structure of [Lu2{Me2pyo[16]trieneN5}2(μ-η 2:η 2-O2)Cl2](ClO4)2(1), where Me2pyo[16]trieneN5 is 2,14-dimethyl-3,6,10,13,19-pentaazabicyclo[13.3.1]nonadeca-1(19),2,13,15,17-pentaene reveals the biologically significant – unprecedented among the lanthanide macrocyclic complexes – planar side-on μ-η 2:η 2 coordination mode of the peroxide as a result of [1 + 1] template Schiff base cyclocondensation of 2,6-diacetylpyridine with 3,7-diazanonane-1,9-diamine in the presence of mixed lutetium chloride and perchlorate salts followed by slow crystallization process.
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Patroniak, V., Kubicki, M. & Radecka-Paryzek, W. The First Example of μ-η 2:η 2-Peroxo-Bridged Macrocyclic Lanthanide Complex. The Crystal Structure of [Lu2{Me2pyo[16]trieneN5}2(μ-η 2:η 2-O2)Cl2](ClO4)2 Dioxane Solvate. Journal of Inclusion Phenomena 49, 121–125 (2004). https://doi.org/10.1023/B:JIPH.0000031124.82412.40
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DOI: https://doi.org/10.1023/B:JIPH.0000031124.82412.40