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The Synthesis of Oxazaborolo-benzoxazaborinine Derivatives of Resorcinarene from (1S,2R)-ephedrine

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Abstract

The oxazaborolo-benzoxazaborinine derivatives (3) of resorcinarene have been synthesized from (1S,2R)-ephedrine. The reaction yields the crown and diamond conformers of the bora derivative of resorcinarene in high diastereomeric excess (de > 97%). The crystallographic structure of the crown conformer of (3) was determined.

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Authors and Affiliations

  1. Institute of Chemistry, Pedagogical University, Chęcińska 5, 25020, Kielce, Poland

    Waldemar Iwanek

  2. Institute of Organic Chemistry, University of Münster, Corrensstrasse 40, 48149, Münster, Germany

    Roland Fröhlich

  3. Institute of Organic Chemistry, University of Tübingen, Auf der Morgenstelle 18, 72076, Tübingen, Germany

    Volker Schurig

Authors
  1. Waldemar Iwanek
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  2. Roland Fröhlich
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  3. Volker Schurig
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Correspondence to Waldemar Iwanek.

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Iwanek, W., Fröhlich, R. & Schurig, V. The Synthesis of Oxazaborolo-benzoxazaborinine Derivatives of Resorcinarene from (1S,2R)-ephedrine. Journal of Inclusion Phenomena 49, 75–79 (2004). https://doi.org/10.1023/B:JIPH.0000031116.87700.f3

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  • DOI: https://doi.org/10.1023/B:JIPH.0000031116.87700.f3

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