Abstract
Bis(4-(4′-nitrophenyl)azo-2-nitrophenyl) disulfide (NADS) has been synthesized for the first time and proposed for the indirect photometric determination of carbon disulfide by dithiocarbamic acid. The reaction, which involves the breaking of the disulfide bond with the formation of colored azothio anions, is carried out in a mixture of dimethylsulfoxide and n-butanol. The high value of the apparent molar absorptivity (2 × 105) is probably due to the autocatalytic character of the reaction. Using NADS, procedures for the determination of carbon disulfide in the atmospheric air of populated areas and in the model gas mixtures designed for the calibration of gas analyzers have been developed and certified. The procedures show high sensitivity and good reproducibility.
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REFERENCES
Murav'eva, S.I., Kaznina, N.I., and Prokhorova, E.K., Spravochnik po kontrolyu vrednykh veshchestv v vozdukhe (Handbook on the Monitoring of Harmful Substances in the Air), Moscow: Khimiya, 1988, p. 130.
Rukovodstvo po kontrolyu zagryazneniya atmosfery. RD [Rukovodyashchii Dokument (Guiding Document)] 52.04.186-89 (A Guide on the Monitoring of Atmospheric Pollution), Moscow: Goskomgidromet SSSR, 1991, p. 209.
Pavlenko, A.A., Vol'berg, N.Sh., and Kotov, V.I., Tr. Glavnoi Geofiz. Observatorii im. A.I. Voeikova, 1984, no. 479, p. 115.
Bulatov, M.I. and Kalinkin, I.P., Prakticheskoe rukovodstvo po fotometricheskim metodam analiza (A Practical Handbook on Photometrical Analysis Techniques), Leningrad: Khimiya, 1986, pp. 35, 45.
Bakulin, S.I., Veksler, K.V., Volkova, E.N., et al., USSR Inventor's Certificate no. 1805358, Byull. Izobret., 1993, no. 12.
Veksler, K.V., Goncharenko, A.G., and Lavrent'ev, A.N., USSR Inventor's Certificate no. 1505945, Byull. Izobret., 1989, no. 33.
Ellamn, G.Z., Arch. Biochem. Biophys., 1958, vol. 74, p. 443; 1959, vol. 82, p. 70.
Novak, J.J., Pleva, S.G., and Epstein, J., Anal. Chem., 1980, vol. 52, no. 12, p. 1851.
Kaji, A., J. Chem. Soc. Japan, Pure Chem. Sect., 1960, no. 81, p. 1776. Cited by Chem. Abstr., 1961, vol. 56, 2391 f.
Bamberger, E. and Hubner, R., Ber. Bunsen-Ges. Phys. Chem., 1903, vol. 36, p. 3808.
Comprehensive Organic Chemistry, The Synthesis and Reactions of Organic Compounds, Barton, D. and Oliss, W.D., Eds., Oxford: Pergamon, 1979, vol. 5. Translated under the title Obshchaya organicheskaya khimiya, Moscow: Khimiya, 1983, vol. 5, p. 457.
Whitesides, G.M., Zikburn, J.E., and Szajewsky, R.P., J. Org. Chem., 1977, vol. 42, no. 2, p. 332.
Stewart, J.J.P., J. Comput. Chem., 1989, vol. 10, p. 209.
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Veksler, K.V., Volkova, E.N., Vol'berg, N.S. et al. Spectrophotometric Determination of Carbon Disulfide Using Bis(4-(4′-Nitrophenyl)azo-2-Nitrophenyl) Disulfide. Journal of Analytical Chemistry 58, 1108–1113 (2003). https://doi.org/10.1023/B:JANC.0000008947.29844.a2
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DOI: https://doi.org/10.1023/B:JANC.0000008947.29844.a2