Skip to main content
Log in

Influence of the Environment on the Atmospheric Corrosion of Bronze

  • Published:
Journal of Applied Electrochemistry Aims and scope Submit manuscript

Abstract

This paper presents a comparative study of the atmospheric corrosion of bronze samples exposed for 12 months, at two sites: an urban atmosphere with intense traffic, in the city of Lisbon, and a rural marine atmosphere, Cabo da Roca, with a high degree of humidity, strong winds and high levels of chlorides all the year round. Exposures were started in the summer. Levels of SO2, NO2 and chlorides, in both atmospheres, were measured during the period of exposure. Climatic data for both sites was also collected and analysed. Weight losses and weight gains of samples with 4, 6, 8 and 12 months of exposure were measured and the average corrosion rates calculated. Chemical composition and morphology of the patinas formed during the exposure period, at both sites, were compared as well as the morphology of the corroded surfaces. Significant differences, related to the level of pollutants and meteorological variables, were found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. T.E. Graedel, K. Nassau and J.P. Franey, Corros. Sci. 27 (1997) 639.

    Google Scholar 

  2. P. Eriksson, L.-G. Johansson and J. Gullman, Corros. Sci. 34 (1993) 1083.

    Google Scholar 

  3. S. Feliu, M. Morcillo and S. Feliu Jr., Corros. Sci. 34 (1993) 415.

    Google Scholar 

  4. S. Oesch and M. Fuller, Corros. Sci. 39 (1997) 1505.

    Google Scholar 

  5. B.I. Rickett and J.H. Payer, J. Electrochem. Soc. 142 (1995) 3713.

    Google Scholar 

  6. M. Morcillo, B. Chico, L. Mariaca and E. Otero, Corros. Sci. 42 (2000) 91.

    Google Scholar 

  7. T.E. Graedel, Corros. Sci. 27 (1997) 7416.

    Google Scholar 

  8. K.P. Fitzgerald, J. Nairn and A. Atrens, Corros. Sci. 40 (1998) 2029.

    Google Scholar 

  9. M. Watanabe, Y. Higashi, T. Tanaka, Corros. Sci. 45 (2003) 1439.

    Google Scholar 

  10. ISO/DIS 9226 'Corrosion of Metals and Alloys. Method of Determination of Corrosion Rate of Standard Speciments for the Evaluation of Corrosovity' (ISO, Geneva, Switzerland, 1987).

    Google Scholar 

  11. ISO/DIS 8565 'Metals and Alloys. Atmospheric Corrosion. General Requirements for Field Tests' (ISO, Geneva, Switzerland, 1990).

    Google Scholar 

  12. R. Amber, British Standards Institute, Pt 4 B5 (1969) 1747.

    Google Scholar 

  13. ISO/DIS 9225, 'Corrosion of Metals and Alloys. Aggressivity of Atmospheres. Methods of Measurements of Pollution Data' (ISO, Geneva, Switzerland, 1987).

    Google Scholar 

  14. F.J. Rossotti and H. Rossotti, J. Chem. Educ. 42 (1965) 375.

    Google Scholar 

  15. D. Shooter, J. Chem. Educ. 5 (1993) A133.

    Google Scholar 

  16. R. Fontinha and M. Salta, Ciência e Tecnologia dos Materiais 13 (2001) 4.

    Google Scholar 

  17. E. Almeida and M. Balmayor, Corros. Prot. Mater. 18 (1999) 6.

    Google Scholar 

  18. ISO /DIS 9223 'Corrosion of Metals and Alloys. Classification of Corrosivity. Categories of Atmospheres' (ISO, Geneva, Switzerland, 1989).

    Google Scholar 

  19. A.C. Ramos, MSc. thesis, University of Lisbon, Portugal (2001).

    Google Scholar 

  20. I.T.E. Fonseca, R. Picciochi, M.H. Mendonça and A.C. Ramos, Corros. Sci. 46 (2003) 547.

    Google Scholar 

  21. R. Picciochi, A.C. Ramos and I.T.E. Fonseca, Portugaliae Electrochim. Acta 20 (2002) 77.

    Google Scholar 

  22. Y. Aoyama, Werkst. Korros. 12 (1961) 148.

    Google Scholar 

  23. D.W. Rice, R.J. Cappell and W. Kinsolving, J. Electrochem. Soc. 127 (1980) 891.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Picciochi, R., Ramos, A., Mendonça, M. et al. Influence of the Environment on the Atmospheric Corrosion of Bronze. Journal of Applied Electrochemistry 34, 989–995 (2004). https://doi.org/10.1023/B:JACH.0000042667.84920.e2

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JACH.0000042667.84920.e2

Navigation