Abstract
The optical spectra of the layered semiconductor BiI3 are calculated in the range 0–6 eV for 6, 77, and 286 K. The spectra are decomposed into transverse and longitudinal components, and their principal parameters are evaluated. The key features of the optical spectra and transitions are compared with the results of band structure calculations.
Similar content being viewed by others
REFERENCES
Tubbs, M.R., The Optical Properties and Chemical Decomposition of the Halides with Layer Structures, Phys. Status Solidi B, 1972, vol. 49, no. 1, pp. 11–50.
Sobolev, V.V., Zony i eksitony galogenidov metallov (Energy Bands and Excitons in Metal Halides), Chisinau: Shtiintsa, 1987.
Lisitsa, M.P. and Motsnyi, F.V., Properties of Bismuth( III) Iodide, Kvantovaya Elektron. (Kiev), 1979, no. 17, pp. 26–45.
Miloslavskii, V.K. and Shmandii, V.M., Anisotropy Effect on the Electronic Spectrum of BiI3, Izv. Akad. Nauk SSSR, Neorg. Mater., 1984, vol. 20, no. 8, pp. 1362–1366.
Vashchenko, V.I., Vorob'ev, V.G., Popov, Yu.V., et al.,Fundamental Reflection Spectra of BiI3 , SbI3, and AsI3 Single Crystals, Izv.Akad. Nauk SSSR, Neorg. Mater.,1971, vol. 7, no. 3, pp. 523-524.
Sobolev, V.V. and Nemoshkalenko, V.V.,Metody vychislitel'noi fiziki v teorii tverdogo tela. Elektronnaya struktura poluprovodnikov(Methods of Computational Physics in the Theory of Solids: Electronic Structure of Semiconductors), Kiev: Naukova Dumka, 1988.
Sobolev, V.V. and Sobolev, V.Val., The Permittivity over a Wide Energy Range of Fundamental Absorption, Neorg. Mater., 1994, vol. 30, no. 8, pp. 1098–1100 [Inorg. Mater. (Engl. Transl.), vol. 30, no. 8, pp. 1016?1017].
Sobolev, V.V., Kalugin, A.J., Sobolev, V.Val., and Kormilets, V.J., Electronic Structure and Optical Properties of Fluorite,J. Wide Bandgap Mater., 2001, vol. 8, no. 2, pp. 87–104.
Sobolev, V.V. and Kalugin, A.I., Optical Properties of Fluorite, Fiz. Tekh. Poluprovodn. (S.-Peterburg), 2002, vol. 36, no. 2, pp. 155–159.
Komatsu, T. and Kaifu, Y., Optical Properties of BiI3, J. Phys. Soc. Jpn., 1976, vol. 40, no. 4, pp. 1062–1068.
Fujita, M., Nakagawa, H., and Kashino, A., Reflection Spectra of BiI3, Annual Report of UVSOR-20, 2000, pp. 46–47.
Pines, D., Elementary Excitations in Solids, New York: Benjamin, 1963. Translated under the title Elementarnye vozbuzhdeniya v tverdykh telakh, Moscow: Mir, 1965.
Sobolev, V.V. and Nemoshkalenko, V.V., Elektronnaya struktura tverdykh tel v oblasti fundamental'nogo kraya pogloshcheniya (Vvedenie v teoriyu) (Electronic Structure of Solids near the Fundamental Absorption Edge: Introduction to Theory), Kiev: Naukova Dumka, 1992, vol. 1.
Schluter, M., Cohen, M.L., Kohn, S.E., and Fong, C.Y., Electronic Structure of BiI3, Phys. Status Solidi B, 1976, vol. 78, no. 2, pp. 737–747.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sobolev, V.V., Pesterev, E.V. & Sobolev, V.V. Temperature Effect on the Optical Properties of BiI3 . Inorganic Materials 40, 878–880 (2004). https://doi.org/10.1023/B:INMA.0000037937.12209.fc
Issue Date:
DOI: https://doi.org/10.1023/B:INMA.0000037937.12209.fc