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Crystal Structures of Zr2Mn12P7 and (Mo,Mn)12P7

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Abstract

Single-crystal x-ray diffraction was used to determine the crystal structures of the ternary phosphides Zr2Mn12P7 (sp. gr. P63/m, a new structure type derived from the Zr2Fe12P7 type,a = 0.9348(2) nm, c = 0.35755(5) nm, R = 0.039, R w = 0.041) and (Mo,Mn)12P7 (sp. gr. P6¯ , a new structure type derived from the Cr12P7 type, a = 0.93242(4) nm,c= 0.33807(1) nm, R = 0.048, R w = 0.049).

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Authors and Affiliations

  1. Franko National University, ul. Kirila i Mefodiya 6, Lviv, 79005, Ukraine

    S. V. Oryshchyn & O. V. Zhak

  2. Laboratoire de Chimie du Solide et Inorganique Moléculaire, UMR CNRS 6511, Université Rennes 1, Campus de Beaulieu, Avenue de Général Leclerc, 35042, Rennes Cedex, France

    S. V. Oryshchyn, S. Deputier, C. Le Sénéchal & R. Guérin

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  1. S. V. Oryshchyn
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  4. C. Le Sénéchal
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Oryshchyn, S.V., Zhak, O.V., Deputier, S. et al. Crystal Structures of Zr2Mn12P7 and (Mo,Mn)12P7 . Inorganic Materials 40, 616–622 (2004). https://doi.org/10.1023/B:INMA.0000031995.10439.0a

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  • DOI: https://doi.org/10.1023/B:INMA.0000031995.10439.0a

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