Sorptive Properties of Shungite

Abstract

Ion exchange and sorption on shungite are studied. The results demonstrate that this mineral is capable of sorbing both inorganic cations and anions. Cation exchange predominates in alkaline solutions, and anion exchange, in acidified solutions. Organic acids are sorbed substantially better; the sorption of aromatic acids by shungite is selective.

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REFERENCES

  1. 1.

    Shungity-novoe uglerodistoe syr'e (Shungite: A New Carboniferous Raw Material), Sokolov, V.A. et al., Eds., Petrozavodsk: Karelia, 1984.

    Google Scholar 

  2. 2.

    Kovalevskii, V.V., Structure of Shungite Carbon, Zh. Neorg. Khim., 1994, vol. 39, no. 1, pp. 31–35.

    Google Scholar 

  3. 3.

    Yushkin, N.P., Globular Supramolecular Structure of Shungite: Scanning Tunneling Microscopy Data, Dokl. Akad. Nauk, 1994, vol. 337, no. 6, pp. 800–803.

    Google Scholar 

  4. 4.

    Buseck, P.R., Tsipursky, S.J., and Hettich, R., Fullerenes from Geological Environment, Science (Washington, D. C., 1883-), 1993, vol. 259, pp. 346–217.

    Google Scholar 

  5. 5.

    Tikhomirova, V.I. and Desyatova, T.A., Iodide-Ion Sorption by Porphyrite and Shungite, Barrier Rocks for High-Activity Waste Disposal, Geokhimiya, 1998, no. 2, pp. 202–208.

  6. 6.

    Yaroslavtsev, A.B., Nikonenko, V.V., and Zabolotskii, V.I., Ionic Transport in Ion-Exchange and Membrane Materials, Usp. Khim., 2003, vol. 73, no. 5, pp. 438–470.

    Google Scholar 

  7. 7.

    Amphlett, C.B., Inorganic Ion Exchangers, Amsterdam: Elsevier, 1964.

    Google Scholar 

  8. 8.

    Boyd, G.E., Adamson, A.W., and Myers, L.S., The Exchange Adsorption of Ions from Aqueous Solutions by Organic Zeolites: II. Kinetics, J. Am. Chem. Soc., 1947, vol. 69, pp. 2836–2845.

    Google Scholar 

  9. 9.

    Yaroslavtsev, A.B., Ion Exchange on Inorganic Sorbents, Usp. Khim., 1997, vol. 66, no. 7, pp. 641–660.

    Google Scholar 

  10. 10.

    Sorokina, N.E., Nikol'skaya, I.V., Ionov, S.G., et al., Acceptor-Type Graphite Intercalation Compounds and New Related Carbon Materials, Usp. Khim., 2004, vol. 73 (in press).

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Shalimov, A.S., Kovalevskii, V.V., Obrezkov, O.N. et al. Sorptive Properties of Shungite. Inorganic Materials 40, 364–367 (2004). https://doi.org/10.1023/B:INMA.0000023956.54637.b8

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Keywords

  • Inorganic Chemistry
  • Organic Acid
  • Cation Exchange
  • Sorb
  • Anion Exchange