Abstract
CdGa2S4 single crystals were grown by the Bridgman–Stockbarger method and chemical vapor transport, and their composition, structure, morphology, and transport properties were studied. The crystals were used for the first time to produce In/CdGa2S4 surface-barrier structures and H2O/CdGa2S4 photoelectrochemical cells. The photoelectric properties of these devices were investigated in unpolarized and linearly polarized light.
Similar content being viewed by others
REFERENCES
Badikov, V.V., Matveev, I.N., Pshenichnikov, S.M., et al., Tunable Narrow-Band Optical Filter Based on Single-Crystal CdGa2S4, Kvantovaya Elektron. (Moscow), 1981, vol. 8, no. 4, pp. 910–912.
Bercha, D.M., Voroshilov, Yu.V., Slivka, V.Yu., and Turyanitsa, I.D., Slozhnye khal'kogenidy i khal'kogalogenidy (Mixed Chalcogenides and Chalcohalides), Lviv, 1983.
Suslikov, L.M., Gad'mashi, Z.P., Kopinets, I.F., and Slivka, V.Yu., Spatial Dispersion Effects in CdGa2S4 Crystals, Opt. Spektrosk., 1981, vol. 51, no. 2, pp. 307–311.
Georgobiani, A.N., Radautsan, S.I., and Tiginyanu, I.M., Wide-Gap II-III2–VI4 Semiconductors: Optical and Photoelectric Properties and Potential Applications, Fiz. Tekh. Poluprovodn. (Leningrad), 1985, vol. 19, no. 2, pp. 193–212.
Areshkin, A.G., Zhitar', V.F., Radautsan, S.I., et al., Direct Excitons in Cadmium Thiogallate, Fiz. Tekh. Poluprovodn. (Leningrad), 1979, vol. 13, no. 2, pp. 337–340.
Georgobiani, A.N., Ozerov, Yu.V., Radautsan, S.I., and Tiginyanu, I.M., Modulation Spectroscopy Study of Fundamental Optical Transitions in CdGa2S4, Fiz. Tverd. Tela (Leningrad), 1981, vol. 23, no. 12, pp. 2094–2099.
Kivits, P., Wijnakker, V., Glassen, J., and Ceerts, J., Photoluminescence and Photoconductivity Measurements on CdGa2S4, J. Phys. C: Solid State Phys., 1978, vol. 11, no. 11, pp. 2361–2368.
Georgobiani, A.N. and Tiginyanu, I.M., Allowed Excitons in CdGa2S4, Kratk. Soobshch. Fiz., 1981, no. 2, pp. 8–13.
Georgobiani, A.N., Radautsan, S.I., and Tiginyanu, I.M., Electroabsorption and Non-Equilibrium Carrier Recombination in CdGa2S4 Single Crystals, Phys. Status Solidi A, 1982, vol. 69, no. 2, pp. 513–520.
Rud', Yu.V. and Tairov, M.A., Photosensitivity of II-IV-V2 Semiconductor/Electrolyte Systems, Fiz. Tekh. Poluprovodn. (Leningrad), 1987, vol. 21, no. 4, pp. 615–619.
Rud', V.Yu., Rud', Yu. V., and Serginov, M., Photoelectric Properties of H2O-p-CdSiAs2:In, Phys. Status Solidi A, 1990, vol. 121, pp. K171–K175.
Rud', Yu.V., Photopleochroism and Physical Principles of Fabricating Semiconductor Polarimetric Photodetectros, Izv. Vyssh. Uchebn. Zaved., Fiz., 1986, no. 8, pp. 68–83.
Guseinova, D.A., Kerimova, T.G., and Nani, R.Kh., Optical Spectra and Band Structure of CdGa2S4 and CdGa2Se4 Single Crystals, Fiz. Tekh. Poluprovodn. (Leningrad), 1977, vol. 11, no. 6, pp. 1135–1142.
Georgobiani, A.N. and Tiginyanu, I.N., Localized States in CdGa2S4, Kratk. Soobshch. Fiz., 1981, no. 2, pp. 3–7.
Panyutin, V.N., Ponedel'nikov, B.E., Rozenson, A.E., and Chizhikov, V.I., Band Structure of Thiogallate-Structure Semiconductors, Izv. Vyssh. Uchebn. Zaved., Fiz., 1979, no. 8, pp. 57–64.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bodnar', I.V., Rud', V.Y. & Rud', Y.V. Growth and Properties of CdGa2S4 Single Crystals. Inorganic Materials 40, 102–106 (2004). https://doi.org/10.1023/B:INMA.0000016081.55152.47
Issue Date:
DOI: https://doi.org/10.1023/B:INMA.0000016081.55152.47