Abstract
Low cohesive strength of grain boundaries and high sensitivity of this parameter to the presence of non-metallic impurities are considered as the causes of grain boundary brittleness and poor workability of refractory fcc-metal iridium. The mechanisms of grain boundary brittleness in both contaminated and non-metallic impurity-free iridium are discussed in the presented paper.
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Brookes, C.A., Greenwood, J.H. and Routbort, J.L. (1968). Brittle fracture in iridium single crystals, J. Appl. Phys. 39, 2391-2395.
Brookes, C.A., Greenwood, J.H. and Routbort, J.L. (1970). The high temperature tensile properties of iridium single crystals, J. Inst. Metals. 98, 27-31.
Chen, S.P. (1992). Studies of iridium interfaces and grain boundaries, Phil. Mag. 66A, 1-10.
Embrittlement of engineering alloys, (1983) (edited by C.L. Bryant and S.K.) Banerji Academic Press, New York.
Handley, J.R. (1986). Increasing application for iridium, Platinum Metals Rev. 30, 12-13.
Hecker, S.S., Rohr, D.L. and Stein, D.F. (1978). Brittle fracture in iridium, Metall. Trans. 9A, 481-488.
Honeycombe, R.W.K. (1972). The plastic deformation of metals, Edward Arnold, London (in Russian: Metallurgia, Moscow).
Gandhi, C. and Ashby, M.F. (1979). On fracture mechanisms of iridium and criteria for cleavage, Scripta Metall. 13, 371-376.
Lynch, S.P. (1988). Ductile and brittle crack growth: fractography, mechanisms and criteria, Materials Forum 11, 268-283.
Mordike, B.L. and Brookes, C.A. (1960). The tensile properties of iridium at high temperatures, Platinum Metals Rev. 4, 94-99.
Panfilov, P., Novgorodov, V. and Yermakov, A. (1994). Fracture behavior of polycrystalline iridium under tension in the temperature range 20–1500 °C, J. Mater. Sci. Lett. 13, 137-141.
Panfilov, P. (2000). On Specific features in mechanical behavior of iridium, Iridium. (Edited by E.K. Ohriner, R.D. Lanam., P. Panfilov and H. Harada), Publication of TMS, USA, 93-100.
Panfilov, P. (2000). Brittle transcrystalline fracture in plastic face-centered cubic metal iridium, Iridium. (Edited by E.K. Ohriner, R.D. Lanam, P. Panfilov and H. Harada), Publication of TMS, USA, 27-40.
Panfilov, P. and Yermakov, A. (2001). Brittle intercrystalline fracture in iridium, Platinum Metals Rev. 45, 179-183.
Panfilov, P. and Yermakov, A. (2002). Brittle transcrystalline and intercrystalline fracture in polycrystalline fcc-metal (iridium), Mechanisms and mechanics of fracture: symposium in the honor of Professor J. F. Knott. (Edited by W.O. Soboyejo, J.J. Lewandowskii and R.O. Ritchie), Publication of TMS, USA, 229-334.
Reid, C.N. and Routbort, J.L. (1972). Malleability and plastic anisotropy of iridium and copper, Metall. Trans. 3, 2257-2260.
Robertson, I.M. and Birnbaum, H.K. (1986). An HVEM study of hydrogen effects on the deformation and fracture of nickel, Acta Metall. 34, 353-366.
Rohr, D.L., Murr, L.E. and Hecker, S.S. (1979). Brittle fracture in polycrystalline Ir-0.3PctW, Metall. Trans. 10A, 399-405.
Timofeev, N., Yermakov, A., Dmitriev, V. and Panfilov, P. (1996). Metallurgy and mechanical behaviour of iridium Urals Branch of Russian Academy of Science, Ekaterinburg, (in Russian).
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Panfilov, P., Yermakov, A. Mechanisms of inherent and impurity-induced brittle intercrystalline fracture in pure FCC-metal iridium. International Journal of Fracture 128, 147–151 (2004). https://doi.org/10.1023/B:FRAC.0000040977.26875.1f
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DOI: https://doi.org/10.1023/B:FRAC.0000040977.26875.1f