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Structure of the Intermediate in the Addition Reaction of Dialkylphosphorous Acids to Grosshemin

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Abstract

The intermediate in the reaction of grosshemin and dialkylphorphorous acids was isolated and characterized structurally. It has been found that addition of a dialkylphosphite anion occurs under these reaction conditions first at an exomethylene and then at the ketone of grosshemin.

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REFERENCES

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Authors and Affiliations

  1. Institute of Phytochemistry, Ministry of Education and Science of the Republic of Kazakhstan, Republic of Kazakhstan, 470032, Karaganda, ul. Gazalieva 4

    S. A. Ivasenko, R. I. Dzhalmakhanbetova, A. T. Kulyyasov & S. M. Adekenov

  2. A. Bekturov Institute of Chemical Sciences, MinistryofEducation and Scienceof the Republic of Kazakhstan, Republic of Kazakhstan, 480100, Almaty, ul. Ualikhanova, 106

    N. B. Kurmankulov

Authors
  1. S. A. Ivasenko
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  2. R. I. Dzhalmakhanbetova
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  3. A. T. Kulyyasov
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  4. N. B. Kurmankulov
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  5. S. M. Adekenov
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Ivasenko, S.A., Dzhalmakhanbetova, R.I., Kulyyasov, A.T. et al. Structure of the Intermediate in the Addition Reaction of Dialkylphosphorous Acids to Grosshemin. Chemistry of Natural Compounds 40, 387–390 (2004). https://doi.org/10.1023/B:CONC.0000048254.86199.10

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  • DOI: https://doi.org/10.1023/B:CONC.0000048254.86199.10

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