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On the Theory of the Stability of Dipole Molecule Solution Interlayers in Apolar Solvents: 2. Diffuse Adsorption Layers

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Abstract

Contribution of the image forces of dipole molecules diffusely distributed over the film thickness to disjoining pressure is considered. Relation for the dependence of this contribution on film thickness is derived. The approach to calculating the constants of dispersion interaction of solute molecules with film-confining phases is developed, and the values of these constants are calculated for a number of systems containing alcohol solutions in hydrocarbons.

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  1. Russian Academy of Sciences, Institute of Physical Chemistry, Leninskii pr. 31, Moscow, 119991, Russia

    L. B. Boinovich & A. M. Emelyanenko

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  1. L. B. Boinovich
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  2. A. M. Emelyanenko
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Boinovich, L.B., Emelyanenko, A.M. On the Theory of the Stability of Dipole Molecule Solution Interlayers in Apolar Solvents: 2. Diffuse Adsorption Layers. Colloid Journal 65, 678–683 (2003). https://doi.org/10.1023/B:COLL.0000009109.74687.cd

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  • DOI: https://doi.org/10.1023/B:COLL.0000009109.74687.cd

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