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Investigation in the Area of Furan Acetal Compounds. 13. Synthesis and Structure of 1,3-Dioxacyclanes Based on Furfural and Glycerol

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The optimum conditions were found for the condensation of glycerol with furfural. It was shown that the reaction of glycerol with furfural gives a mixture of the cis and trans isomers of five- and six-membered furan 1,3-dioxacyclanes. The cis- and trans-5-hydroxy-2-furyl-1,3-dioxanes were isolated by column chromatography, and their stereochemical structure was established by IR and NMR spectroscopy.

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Authors and Affiliations

  1. Kuban State Technological University, Krasnodar, 350072, Russia

    E. V. Gromachevskaya, F. V. Kvitkovsky, E. B. Usova & V. G. Kulnevich

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  1. E. V. Gromachevskaya
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  2. F. V. Kvitkovsky
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  3. E. B. Usova
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  4. V. G. Kulnevich
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Gromachevskaya, E.V., Kvitkovsky, F.V., Usova, E.B. et al. Investigation in the Area of Furan Acetal Compounds. 13. Synthesis and Structure of 1,3-Dioxacyclanes Based on Furfural and Glycerol. Chemistry of Heterocyclic Compounds 40, 979–985 (2004). https://doi.org/10.1023/B:COHC.0000046685.17653.c4

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