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Determination of the 13C chemical shift anisotropies of cellulose I and cellulose II

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Abstract

The chemical shift anisotropies (CSAs) of cellulose Iα and Iβ, the two crystalline constituents of bacterial cellulose produced by Acetobacter xylinum (DSM 14666), and regenerated cellulose II are reported for each of the spectroscopically resolved carbon resonances using the phase adjusted spinning sideband (PASS) experiment. The data are compared with experimental results using the recoupling of anisotropy information (RAI) technique and with theoretical calculations of the structure of cellulose, including the hydrogen bonding systems.

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Authors and Affiliations

  1. Institute of Optics and Quantum Electronics, Friedrich-Schiller-Universität Jena, Max-Wien-Platz 1, D-07743, Jena, Germany

    Stephanie Hesse

  2. Centre of Excellence for Polysaccharide Research, Friedrich-Schiller-Universität Jena, Lessingstrasse 8, D-07743, Jena, Germany

    Stephanie Hesse

  3. Project Group I.3903, Federal Institute for Materials Research and Testing, Richard Willstaetter Strasse 11, D-12489, Berlin, Germany

    Christian Jäger

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  1. Stephanie Hesse
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  2. Christian Jäger
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Hesse, S., Jäger, C. Determination of the 13C chemical shift anisotropies of cellulose I and cellulose II. Cellulose 12, 5–14 (2005). https://doi.org/10.1023/B:CELL.0000049407.56737.c7

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  • DOI: https://doi.org/10.1023/B:CELL.0000049407.56737.c7

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