Abstract
Ethylene glycol was prepared by hydration of ethylene oxide over highly efficient supported niobia catalyst prepared by chemical vapor deposition. The catalyst showed much better hydration performance in activity and selectivity than other solid acid catalysts. An ethylene glycol yield of 91% was achieved at optimal conditions.
Similar content being viewed by others
References
V. Kruchten, WO Patent 9,719,043 (1997).
T. Masuda, K. Asano, N. Hori and S. Ando, Jpn. Kokai Tokkyo Koho JP 62, 126,144, (1987).
T. Masuda, K. Asano, N. Hori and S. Ando, US Patent 4,937,393 (1990).
T. Masuda, K. Asano, N. Hori and S. Ando, Eur. Patent 226,799 (1992)
L. Kim, US Patent 4,165,440 (1979).
JohnsonJr., L. Fred, Watts Jr. and W. Lewis, US Patent 4,393,254 (1983).
Q.S. Lin, S.M. Li, B. Zhou, Z.H. Zhou, Y.R. Zhang, Y.B. Zhang, X.P. Wang, X.C. Zhou, Y.H. Wang and G. Chen, CN Patent 1,237,481 (1999).
I. Nowak and M. Ziolek, Chem. Rev. 99 (1999) 3603–3624.
K. Tanabe (ed.) Catal. Today 28 (1996).
T. Hanaoka, K. Takeuchi, T. Matsuzaki and Y. Sugi, Catal. Today 8 (1990) 123–132.
T. Hanaoka, K. Takeuchi, T. Matsuzaki and Y. Sugi, Catal. Lett. 5 (1990) 13–16.
T. Hanaoka, K. Takeuchi, T. Matsuzaki and Y. Sugi, Jpn. Kokai Tokkyo Koho JP 6,179,633 (1994).
C.L. Tavares da Silva, V.L.L. Camorim, J.L. Zotin and M.L.R. Duarte, Catal. Today 57 (2000) 209–217.
Y. Izumi, Catal. Today 33 (1997) 392–393.
Izumi,Handbook of X-ray Photoelectron Spectroscopy, (Perkin-Elmer Corporation, 1992).
L. Dragone, P. Moggi, G. Predieri and R. Zanoni, Appl. Surf. Sci. 187 (2002) 82–88.
Y. Gao, Y. Liang and S.A. Chambers, Surf. Sci. 348 (1996) 17–27.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Li, Y., Yue, B., Yan, S. et al. Preparation of Ethylene Glycol via Catalytic Hydration with Highly Efficient Supported Niobia Catalyst. Catalysis Letters 95, 163–166 (2004). https://doi.org/10.1023/B:CATL.0000027290.25879.f2
Issue Date:
DOI: https://doi.org/10.1023/B:CATL.0000027290.25879.f2