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Synthesis and Characterization of Highly Dispersed Molybdenum Carbides in Mesoporous Silica

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Abstract

Highly dispersed molybdenum carbides in MCM-41 mesoporous silica are synthesized by temperature-programmed carburization and are characterized. Two methods of preparation are examined: (i) insertion of molybdenum during the synthesis of the MCM-41 silica and (ii) postsynthesis incorporation into a MCM-41 silica matrix by the incipient wetness method. Propene transformation (hydrogenation and metathesis) was used as a probe reaction; the observed catalytic behavior can be explained as a result of the preparation method, i.e., of the relative strength of interaction between the molybdenum oxide precursor and the support.

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References

  1. T. Yanagisawa, T. Shimizu, K. Kuroda and C. Kato, Bull. Chem. Soc. Jpn. 63 (1990) 988.

    Google Scholar 

  2. T. Yanagisawa, T. Shimizu, K. Kuroda and C. Kato, Bull. Chem. Soc. Jpn. 63 (1990) 1535.

    Google Scholar 

  3. C.T. Kresge, M.E. Leonowicz, J.W. Roth, J.C. Vartuli and J.S. Beck, Nature 359 (1992) 710.

    Google Scholar 

  4. J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins and J.L. Schlenker, J. Am. Chem. Soc. 114 (1992) 10834.

    Google Scholar 

  5. A. Stein, B.J. Melde and R.C. Schroden, Adv. Mater. 12 (2000) 1403.

    Google Scholar 

  6. A. Sayari, Chem. Mater. 8 (1996) 1840.

    Google Scholar 

  7. A. Corma, A. Martinez, V. Martinez-Soria and J.B. Monton, J. Catal. 153 (1995) 25.

    Google Scholar 

  8. A. Wang, Y. Wang, T. Kabe, Y. Chen, A. Ishihara, W. Qian and P. Yao, J. Catal. 210 (2002) 319.

    Google Scholar 

  9. D.-H. Cho, T.-S. Chan, S.-K. Ryu and Y.K. Lee, Catal. Lett. 64 (2000) 27.

    Google Scholar 

  10. K.R. Rana and B. Viswanathan, Catal. Lett. 52 (1998) 25.

    Google Scholar 

  11. J.-Y. Piquemal, J.-M. Manoli, P. Beaunier, A. Ensuque, P. Tougne, A.-P. Legrand and J.-M. Brégeault, Microporous Mesoporous Mater. 29 (1999) 291.

    Google Scholar 

  12. J.-Y. Piquemal, E. Briot, M. Vennat, J.-M. Brégeault, G. Chottard and J.-M. Manoli, Chem. Commun. (1999) 1195.

  13. E. Briot, J.-Y. Piquemal, M. Vennat, J.-M. Brégeault, G. Chottard and J.-M. Manoli, J. Mater. Chem. 10 (2000) 953.

    Google Scholar 

  14. S.T. Oyama, Catal. Today 2 (1992) 179.

    Google Scholar 

  15. J.S. Lee, M.H. Yeom, K.Y. Park, I.S. Nam, J.S. Chung, Y.G. Kim and S.H. Moon, J. Catal. 128 (1991) 126.

    Google Scholar 

  16. S.T. Oyama, J.C. Schlatter, J.E. Metcalfe and J.M. Lambert, Ind. Eng. Chem. Res. 27 (1988) 1639.

    Google Scholar 

  17. L. Volpe and M. Boudart, Catal. Rev. Sci. 27 (1985) 515.

    Google Scholar 

  18. P.D. Costa, C. Potvin, J.-M. Manoli, J.-L. Lemberton, G. Pérot and G. Dgéga-Mariadassou, J. Mol. Catal., A 184 (2002) 323.

    Google Scholar 

  19. Q. Huo, D.I. Margolese, U. Ciesla, D.G. Demuth, P. Feng, T.E. Gier, P. Sieger, A. Firouzi, B.F. Chmelka, F. Schüth and G.D. Stucky, Chem. Mater. 6 (1994) 1176.

    Google Scholar 

  20. S. Brunauer, P.H. Emmett and E. Teller, J. Am. Chem. Soc. 60 (1938) 309.

    Google Scholar 

  21. E.P. Barrett, L.G. Joyner and P.P. Halenda, J. Am. Chem. Soc. 73 (1951) 373.

    Google Scholar 

  22. M. Kruk, M. Jaroniec and A. Sayari, Microporous Mater. 9 (1997) 173.

    Google Scholar 

  23. R.L. Burwell, Langmuir 2 (1986) 2.

    Google Scholar 

  24. B. Marler, U. Oberhagemann, S. Vortmann and H. Gies, Microporous Mater. 6 (1996) 375.

    Google Scholar 

  25. C. Bouchy, S.B.D.-A. Hamid and E.G. Derouane, Chem. Commun. (2000) 125.

  26. S. Yuan, S.B.D.-A. Hamid, Y. Li, P. Ying, Q. Xin, E.G. Derouane and C. Li, J. Mol. Catal., A 184 (2002) 257.

    Google Scholar 

  27. M. Cheng, F. Kumata, T. Saito, T. Komatsu and T. Yashima, in Studies in Surface Science and Catalysis, L. Bonneviot, F. Béland, C. Danumah, S. Giasson and S. Kaliaguine (eds) (Elsevier, Amsterdam, 1998) p. 485.

    Google Scholar 

  28. M.S. Morey, J.D. Bryan, S. Schwartz and G.D. Stucky, Chem. Mater. 12 (2000) 3435.

    Google Scholar 

  29. L.-X. Dai, Y.-H. Teng, K. Tabata, E. Suzuki and T. Tatsumi, Microporous Mesoporous Mater. 44-45 (2001) 573.

    Google Scholar 

  30. S. Che, Y. Sakamoto, H. Yoshitake, O. Terasaki and T. Tatsumi, J. Phys. Chem. 105 (2001) 10565.

    Google Scholar 

  31. C.C. Williams, J.G. Ekerdt, J.-M. Jehng, F.D. Hardcastle, A.M. Turek and I.E. Wachs, J. Phys. Chem. 95 (1991) 8781.

    Google Scholar 

  32. J.M. Stencel, Raman Spectroscopy for Catalysis (Van Nostrand Reinhold, New York, 1990).

    Google Scholar 

  33. J.L. Hérisson and Y. Chauvin, Makromol. Chem. 141 (1970) 161.

    Google Scholar 

  34. I. Rodriguez-Ramos, A. Guerrero-Ruiz, N. Homs, P. Ramírez de la Piscina and J.L.G. Fierro, J. Mol. Catal., A: Chem. 95 (1995) 147.

    Google Scholar 

  35. A.K. Rappé and W.A.G. III, J. Am. Chem. Soc. 104 (1982) 448.

    Google Scholar 

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Authors and Affiliations

  1. Laboratoire ITODYS –LCMDC, Université Denis Diderot, CNRS UMR 7086, Case 7090, 2 place Jussieu, 75251, Paris cedex 05, France

    Jean-Yves Piquemal

  2. Laboratoire de Réactivité de Surface, Université Pierre et Marie Curie, CNRS - UMR 7609, Case 178, 4 place Jussieu, 75252, Paris cedex 05, France

    Claude Potvin, Jean-Marie Manoli & Gérald Djéga-Mariadassou

Authors
  1. Jean-Yves Piquemal
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  2. Claude Potvin
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  3. Jean-Marie Manoli
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  4. Gérald Djéga-Mariadassou
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Correspondence to Jean-Marie Manoli.

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Piquemal, JY., Potvin, C., Manoli, JM. et al. Synthesis and Characterization of Highly Dispersed Molybdenum Carbides in Mesoporous Silica. Catalysis Letters 92, 189–195 (2004). https://doi.org/10.1023/B:CATL.0000014345.69368.76

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