Abstract
Technical improvement of the photoluminescence cell and its coupling to a dynamic vacuum system allow to avoid quenching phenomena. These results in emission spectra of MgO, which are better-resolved and more stable in time, leading to a better characterization of the very reactive oxide ions, i.e., those in low coordination. Apart from a more precise assignment of the spectra, new developments are proposed to evaluate the relative distribution of ions of low coordination. Discrimination of the oxide ions with different coordination numbers is also possible by studying in situ their interaction with propyne as a probe molecule.
Similar content being viewed by others
References
M. Che and A.J. Tench, Adv. Catal. 31 (1982) 77.
M. Anpo and M. Che, Adv. Catal. 44 (1999) 119.
Y. Kubokawa and M. Anpo, in Adsorption and Catalysis on Oxide Surfaces, M. Che and G.C. Bond (eds), (Elsevier, Amsterdam, 1985) p. 127.
A.J. Tench and R.L. Nelson, Trans. Faraday Soc. 63 (1967) 2254.
M. Anpo, M. Sunamoto and M. Che, J. Phys. Chem. 93 (1989) 1187.
S. Coluccia, A.J. Tench and R.L. Segall, J. Chem. Soc., Faraday Trans. I 75 (1979) 1769.
M. Anpo, M. Sunamoto, T. Doi and I. Matsuura, Chem. Lett. 4 (1998) 7014.
W.W. Duley, Phil. Mag. B49 (1984) 159.
A.L. Shluger, P.V. Sushko and L.N. Kantorovich, Phys. Rev. B59 (1999) 2417.
S. Coluccia, A. Barton and A.J. Tench, J. Chem. Soc., Faraday Trans. I 77 (1981) 2203.
H. Idriss and M.A. Barteau, J. Phys. Chem. 96 (1992) 3382.
N.J. Turro, Molecular Photochemistry (Benjamin, New York, 1967).
N.J. Turro, Modern Molecular Photochemistry (Benjamin/Cummings, Menlo Park, CA, 1978).
S. Coluccia, A.M. Deane and A.J. Tench, J. Chem. Soc. Faraday Trans. I 74 (1978) 2913.
M. Anpo and Y. Kubokawa, J. Phys. Chem. 88 (1984) 5556.
M. Anpo, M. Kondo, S. Coluccia, C. Louis and M. Che, J. Am. Chem. Soc. 111 (1989) 8791.
M. Anpo, Y. Yamada, Y. Kubokawa, S. Coluccia, A. Zecchina and M. Che, J. Chem. Soc., Faraday Trans. I 84 (1988) 751.
A. Zecchina and F.S. Stone, J. Chem. Soc. Faraday Trans. I 72 (1976) 2364.
V.R. Choudhary and M.Y. Pandit, Appl. Catal. 71 (1991) 265.
E. Garrone, A. Zecchina and F.S. Stone, Phil. Mag. B42 (1980) 683.
M.L. Bailly, G. Costentin, H. Lauron-Pernot, J.M. Krafft and M. Che, in preparation
M.L. Bailly, G. Costentin, H. Lauron-Pernot, J.M. Krafft and M. Che, in preparation
M. Anpo, I. Tanahashi and Y. Kubokawa, J. Phys. Chem. 84 (1980) 3440.
M. Anpo, I. Tanahashi and Y. Kubokawa, J. Phys. Chem. 86 (1986) 1.
B. Shelimov, V. Dellarocca, G. Martra, S. Coluccia and M. Che, Catal. Lett. 87 (2003) 73.
M.L. Bailly, G. Costentin, H. Lauron-Pernot, J.M. Krafft, P. Bazin, J. Saussey and M. Che, in preparation
H. Knözinger and S. Huber, J. Chem. Soc., Faraday Trans. I 94 (1998) 2047.
J.C. Lavalley, Catal. Today 27 (1996) 377.
C. Binet, A. Jadi, J. Lamotte and J.C. Lavalley, J. Chem. Soc., Faraday Trans. I 92 (1996) 123.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Bailly, ML., Costentin, G., Krafft, J.M. et al. Discrimination of MgO Ions by Means of an Improved In Situ Photoluminescence Cell and of Propyne as Probe Molecule. Catalysis Letters 92, 101–105 (2004). https://doi.org/10.1023/B:CATL.0000014331.73108.67
Issue Date:
DOI: https://doi.org/10.1023/B:CATL.0000014331.73108.67