Abstract
The kinetics of epoxidation of 1-octene by tert-butyl hydroperoxide in the presence of molybdenum boride (Mo2B) was studied. The effects of reactant and reaction product concentrations on the process were examined. A kinetic scheme was proposed, and the kinetic parameters of the process were calculated.
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REFERENCES
Trach, Yu., Nykypanchuk, M., and Komarenska, Z., Pol. J. Chem., 2002, vol. 76, p. 1323.
Timofeev, S.V., Smirnova, A.L., Filippova, T.V., and Blyumberg, E.A., Kinet. Katal., 1992, vol. 33, no. 1, p. 105.
Filippova, T.V., Timofeev, S.V., Smirnova, A.L., and Blyumberg, E.A., Kinet. Katal., 1992, vol. 33, no. 1, p. 114.
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Trach, Y.B., Nikipanchuk, M.V. & Komarenskaya, Z.M. Reaction Kinetics of the Hydroperoxide Epoxidation of 1-Octene in the Presence of Mo2B. Kinetics and Catalysis 45, 504–507 (2004). https://doi.org/10.1023/B:KICA.0000038077.72162.54
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DOI: https://doi.org/10.1023/B:KICA.0000038077.72162.54