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Journal of Thermal Analysis and Calorimetry

, Volume 78, Issue 1, pp 173–184 | Cite as

Characterization of Bio-Fuel and Bio-Fuel Ash

  • Q. S. M. Kwok
  • D. E. G. Jones
  • G. F. Nunez
  • J. P. Charland
  • S. Dionne
Article

Abstract

Three bio-fuels with or without additives and their fly ash samples were characterized using simultaneous Thermogravimetry-Differential Thermal Analysis-Fourier Transform Infrared Spectrometry-Mass Spectrometry (TG-DTA-FTIR-MS), X-ray Diffraction (XRD), X-ray Fluorescence (XRF), and Scanning Electron Microscopy-Energy Dispersive Spectrometry (SEM-EDS). The results show that the additives increase the reactivity of the bio-fuel during combustion. The additives also significantly decrease the amount of unburned carbon in the fly ash. The additives affect the compounds formed in the fly ash sample, and consequently the thermal behaviour of the fly ash. The fly ash samples are thermally stable in air up to 100°C. The fly ash samples contain fine particles with irregular shape, small round particles, and large hollow spherical particles with entrapped gases.

thermal analysis combustion composition fly ash bio-fuel 

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References

  1. 1.
    A.V. Bridgwater, D. Meier and D. Radlein, Org. Geochem., 30 (1999) 1479.CrossRefGoogle Scholar
  2. 2.
    K. Sipila, E. Kuoppala, L. Fagernas and A. Oasmaa, Biomass Bioenergy, 14 (1998) 103.CrossRefGoogle Scholar
  3. 3.
    A. Oasmaa and S. Czernik, Energy Fuels, 13 (1999) 914.CrossRefGoogle Scholar
  4. 4.
    ASTM E967-03, Standard Practice for Temperature Calibration of Differential Scanning Calorimeters and Differential Thermal Analyzers, American Society for Testing and Materials, West Conshohocken, PA, USA.Google Scholar
  5. 5.
    ASTM D4326-03, Standard Test Method for Major and Minor Elements in Coal and Coke Ash by X-Ray Fluorescence, American Society for Testing and Materials, West Conshohocken, PA, USA.Google Scholar
  6. 6.
    P. K. Kolay and D. N. Singh, Cem. Concr. Res., 31 (2001) 539.CrossRefGoogle Scholar
  7. 7.
    S. V. Vassilev and C. G. Vassileva, Fuel Process. Technol., 47 (1996) 261.CrossRefGoogle Scholar

Copyright information

© Kluwer Academic Publisher/Akadémiai Kiadó 2004

Authors and Affiliations

  • Q. S. M. Kwok
    • 1
  • D. E. G. Jones
    • 1
  • G. F. Nunez
    • 2
  • J. P. Charland
    • 1
  • S. Dionne
    • 1
  1. 1.Natural ResourcesOttawa, OntarioCanada K1A 0G1 E-mail
  2. 2.Orenda Aerospace CorporationGloucester, OntarioCanada K1J 9L8

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