Abstract
The sorption and determination of mercury(II) on the solid phase of a fibrous polyacrylonitrile material filled with the AV-17 anion exchanger is studied. Mercury is adsorbed in the form of the chloride complex from a solution with pH 5–7.5; it is determined on the solid phase by the reaction with dithizone either visually or by the measuring the color hue. A procedure for the test determination of mercury(II) has been developed and tested in the analysis of fresh natural waters by the added–found method. The detection limit is 0.02 mg/L. The time of analysis of 5 or 6 samples is no more than 15–20 min.
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REFERENCES
Fresenius, W. and Dylick, C.E., Fresenius' J. Anal. Chem., 2000, vol. 366, no. 5, p. 417.
Danilova, V.N., Khushvakhtova, S.D., Koshcheeva, I.Ya., and Kholin, Yu.V., Abstracts of papers, Mezhdunarodnyi sympozium: Razdelenie i kontsentrirovanie v analiticheskoi khimii (Int. Symp.: Separation and Preconcentration in Analytical Chemistry), Krasnodar, 2002, p. 165.
Zolotov, Yu.A., Ivanov, V.M., and Amelin, V.G., Khimicheskie test-metody analiza (Chemical Test Methods of Analysis), Moscow: URSS, 2002.
Ostrovskaya, V.M., Aksenova, M.S., Osyka, V.F., et al., Vysokochist. Veshchestva, 1992, no. 3, p. 152.
Amelin, V.G., Zh. Anal. Khim., 1999, vol. 54, no. 6, p. 651; no. 7, p. 753; no. 10, p. 1088.
Yallouz, A.V., Campos, R.C., and Paciornik, S., Fresenius' J. Anal. Chem., 2000, vol. 366, no. 5, p. 461.
Zaporozhets, O., Petruniok, N., and Sukhan, V., Talanta, 1999, vol. 50, no. 4, p. 865.
Tikhomirova, T.I., Kuznetsov, M.V., Fadeeva, V.I., and Ivanov, V.M., Zh. Anal. Khim., 2000, vol. 55, no. 8, p. 816.
Ivanov, V.M. and Kochelaeva, G.A., Vestn. Mosk. Univ., Ser. 2: Khim., 2001, vol. 42, no. 1, p. 17.
Mikhailova, A.V., Shkinev, V.M., and Savvin, S.B., Abstracts of Papers, II Vseross. simpozium: Protochnyi khimicheskii analiz (II All-Russ. Symp.: Chemical Flow Analysis), Moscow, 1999, p. 68.
Gur'eva, R.F., Savvin, S.B., and Mikhailova, A.V., Abstracts of Papers, Mezhdunarodnyi sympozium: Razdelenie i kontsentrirovanie v analiticheskoi khimii (Int. Symp.: Separation and Preconcentration in Analytical Chemistry), Krasnodar, 2002, p. 49.
Gotzl, A. and Riepe, W., Talanta, 2001, vol. 54, no. 5, p. 821.
Shvoeva, O.P., Dedkova, V.P., Gitlits, A.G., and Savvin, S.B., Zh. Anal. Khim., 1997, vol. 52, no. 1, p. 89.
Ahmad, M., Hamzah, H., and Mazsom, E.S., Talanta, 1999, vol. 47, no. 2, p. 275.
Shekhovtsova, T.N., Muginova, S.V., Veselova, I.A., and Dolmanova, I.F., Zh. Anal. Khim., 2002, vol. 57, no. 12, p. 1308.
Shvoeva, O.P., Dedkova, V.P., and Savvin, S.B., Zh. Anal. Khim., 2003, no. 6, p. 590.
Perel'man, A.I., Geokhimiya landshaftov rudnykh provintsii (Geochemistry of Landscapes of Ore Provinces), Moscow: Nauka, 1982.
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Dedkova, V.P., Shvoeva, O.P. & Savvin, S.B. Test Method for the Determination of Mercury(II) with Dithizone on the Solid Phase of a Fibrous Anion Exchanger. Journal of Analytical Chemistry 59, 381–385 (2004). https://doi.org/10.1023/B:JANC.0000022793.59702.ab
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DOI: https://doi.org/10.1023/B:JANC.0000022793.59702.ab