Abstract
The corrosion and inhibition behavior of mild steel in 1 M HCl in the presence of poly(4-vinylpyridine)(P4VP) and potassium iodide (KI) was investigated using weight loss measurements, potentiodynamic polarization studies and impedance measurements. The inhibition efficiency increased with increasing P4VP concentration. The inhibiting action of P4VP is considerably enhanced by the addition of potassium iodide. The adsorption of this compound either alone or in combination with iodide ions on the metal surface is found to obey Lamgmir's adsorption isotherm. The experimental results suggest that the presence of iodide ions in the solution increases the surface coverage Θ and, therefore, indicate the joint adsorption of P4VP and iodide ions. On the other hand, it was found that the inhibiting effect of P4VP and (P4VP + KI) increased with increasing temperature of the corrosion medium. The presence of these species in the solution decreases the double layer capacitance and increases the charge transfer resistance, both derived from Nyquist plots obtained from a.c. impedance studies. The variation of charge transfer resistance with time suggests that the inhibitive action of (P4VP + KI) depends mainly on the protective inhibitor film formed on the steel surface.
Similar content being viewed by others
References
G. Schmitt, Br. Corros. J. 19(4) (1984) 165.
A. El Sayed, J. Appl. Electrochem. 27(2) (1997) 193.
J.M. Sykes, Br. Corros. J. 25(3) (1990) 175.
M. Ajmal, A.S. Mideen and M.A. Quraishi, Corros. Sci. 36(1) (1994) 79.
G.K. Gomma and M.H. Wahdan, Bull. Chem. Jpn 67 (1994) 2621.
F. Bentiss, M. Traisnel and M. Lagrenee, {tiCorros. Sci.} 42(1) (2000) 127.
A.S. Fouda, M.M. Gouda and S.I. Abd El-Rahman, Bull. Korean Chem. Soc. 21(11) (2000) 1085.
X.L. Cheng, H.Y. Ma, S.H. Chen, R.Yu, X. Chen and Z.M. Yao, Corros. Sci. 41(2) (1999) 321.
M. Ajmal, J. Rawat and M.A. Quraishi, Br. Corros. J. 34(3) (1999) 220.
M.A. Quraishi, M.A. Wajid Khan, M. Ajmal, S. Muralidharan and S. Venkatakrishna Iyer, Br. Corros. J. 32(1) (1997) 72.
R. Agrawal and T.K.G. Namboodhiri, Corros. Sci. 30(1) (1990) 37.
S. Kertit and B. Hammouti, Appl. Surf. Sci. 93(6) (1996) 59.
Y. Tianguo, W. Lin, V. Otieno-alego and D.P. Schweinsberg, Corros. Sci. 37(6) (1997) 975.
D.P. Schweinsberg, A. Trueman and V. Otreno-Alego, Corros. Sci. 38(4) (1996) 587.
M.B. Abo El-Khair and B. Mostafa, Corros. Prev. Control 30 (1983) 14.
J. Jang and H. Ishida, Corros. Sci. 33(7) (1992) 1053.
M.N. Desai, B.C. Thakar, P.M. Chhaya and M.H. Gandhi, Corros. Sci. 16(1) (1976) 9.
A.A. Abd El Fattah, K.M. Atia, F.S. Ahmed and M.I. Roushdy, Corros. Prev. Control 33(3) (1986) 67.
R.R. Annand, R.M. Hurd and N. Hackerman, J. Electrochem. Soc. 112(2) (1965) 138.
M.B. Abo El-Khair, B. Mostafa, O.R. Khalifa, I.A. Abdel-Hamid and A.M. Azzam, Corros. Prev. Control 34(6) (1987) 152.
H. Okahara, R. Ueda, M. Kozai, Y. Matsuda, Y. Kera and M. Kamata, Hyomen Gijutsu 46(9) (1995) 851.
V.I. Zavrazhina, Yu.N. Mikhailovskii and P.I. Zubov, Zashchita Metallov 3(6) (1967) 700.
H. Okahara, M. Kozai and Y. Matsuda, Hyomen Gijutsu 45(11) (1994) 1164.
O.R. Khalifa, I.A. Abdul Hamid, S.M. Mokhtar and A.A. Kassab, Asian J. Chem. 5(3) (1993) 749.
M.B. Abo El-Khair, B. Mostafa, S.M. Abdel Wahaab and E.M. Mabrouk, Surf. Coat Technol. 27(4) (1986) 317.
Y. Abed, Z. Arrar, B. Hammouti, A. Aouniti, S. Kertit and A. Mansri, J. Chem. Phys. 96(8) (1999) 1347.
Y. Abed, B. Hammouti, F. Touhami, A. Aouniti, S. Kertit, A. Mansri and K. Elkacemi, Bull. Electrochem. 17(3) (2001) 105.
Y. Abed, Z. Arrar, B. Hammouti, M. Taleb, S. Kertit and A. Mansri, {tiAnti. Corros. Meth. Mat.} 48(5) (2001) 304.
Yu.E. Kirsh, S.K. Plujhnov, T.S. Shomina, V.A. Kabanov and V.A. Karjin, Vysokomolek Soedin A 12(1) (1970) 186.
Yu.E. Kirsh, O.P. Komarova and G.M. Lukovkin, Eur. Polym. J. 9(12) (1973) 1405.
T. Tsuru, S. Haruyama and Boshoku Gijutsu, J. Jpn Soc. Corros. Eng. 27(1978) 573.
M.B. Abo El-Khair and I.A. Abdel Hamed, Corros. Sci. 16 (1976) 169.
K. Aramaki and N. Hackerman, J. Electrochem. Soc. 116 (1969) 568.
Z.S. Syed, S. Muralidharan, S. Venkatakrishna Iyer, B. Muralidharan and T. Vasudevan, Br. Corros. J. 33(4) (1998) 297.
F. Mansfeld, M.W. Kendig and S. Tsai, Corrosion 38(9) (1982) 570.
G. Perboni and G. Rocchini, 10th ICMC, Madras, India, 1988, p. 193.
O. Riggs, I.R. Hurd and M. Ray, Corrosion 23(9) (1967) 252.
S. Martinez, Matér. Chem. Phys.77(1) (2003) 97.
T. Szauer and A. Brandt, Electrochim. Acta 26(9) (1981) 1209.
Z.A. Foroulis, Proceedings of the 6th European Symposium on Corrosion Inhibitors, Ferrara, 1985, p. 48.
I.A. Ammar and F.M. El Khorafi, Werkstoffe und Korrosion 24(8) (1973) 702.
E.S. Ivanov, 'Inhibitors of Corrosion of Metals in Acid Media, Metallurgy, Handbook in Accordance with the State Service of Standard Reference Data' (Moscow 1986) 175 pp.
I.N. Putilova, S.A. Balezin, V.P. Barrannik and E. Bishop, 'Metallic Corrosion Inhibitors' (Pergamon Press, New York 1960) 196 pp.
R.F.V. Villamil, P. Corio, J.C. Rubim and S.M.L. Agostinho, J. Electroanal. Chem. 535 (2002) 75.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Larabi, L., Harek, Y., Traisnel, M. et al. Synergistic Influence of Poly(4-Vinylpyridine) and Potassium Iodide on Inhibition of Corrosion of Mild Steel in 1M HCl. Journal of Applied Electrochemistry 34, 833–839 (2004). https://doi.org/10.1023/B:JACH.0000035609.09564.e6
Issue Date:
DOI: https://doi.org/10.1023/B:JACH.0000035609.09564.e6