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X-ray structure of {[μ-N,N′-Bis(salicylidene)-1, 3-propane-diamine] (dimethylformamide) zinc(II)} dibromo cadmium(ii)

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Abstract

The title compound, forms crystals which are the orthorhombic system, space group P2 12121, with unit cell dimensions a = 10.3928(12) Å, b = 14.6298(13) Å, c = 15.9514(11) Å, V = 2425.3(4) Å3. The cell contains four molecules. The structure is a heteronuclear dimeric complex with ZnII and CdII ions. The coordination around the ZnII ion is distorted square–pyramid and the CdII ion is distorted tetrahedral coordination. The Zn·sCd distance is 3.3594(7) Å.

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Authors and Affiliations

  1. Department of Engineering Physics, University of Hacettepe, Ankara, Turkey

    Cengiz Arıcı & Dinçer Ülkü

  2. Department of Chemistry, Faculty of Science, University of Erciyes, Yozgat, Turkey

    Mecit Aksu

  3. Department of Chemistry, University of Ankara, Ankara, Turkey

    Orhan Atakol

Authors
  1. Cengiz Arıcı
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  2. Dinçer Ülkü
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  3. Mecit Aksu
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  4. Orhan Atakol
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Correspondence to Cengiz Arıcı.

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Arıcı, C., Ülkü, D., Aksu, M. et al. X-ray structure of {[μ-N,N′-Bis(salicylidene)-1, 3-propane-diamine] (dimethylformamide) zinc(II)} dibromo cadmium(ii). Journal of Chemical Crystallography 33, 825–829 (2003). https://doi.org/10.1023/A:1027497427264

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