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Reactions of [Mn2(μ-pyS)2(CO)6] with bidentate N-donor ligands: Crystal structure of [Mn(η1-pyS)(bipy)(CO)3] (bipy = 2,2′-bipyridyl, pySH = pyridine-2-thiol)

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Abstract

The dimeric complex [Mn2(μ-pyS)2(CO)6] (1) reacted with 2 equivalents of 2,2′-bipyridyl (bipy), 1,10-phenanthroline (phen), and ethylenediamine (en) to give the corresponding monomeric complexes [Mn(η1-pyS)(bipy)(CO)3] (2), [Mn(η1-pyS)(phen)(CO)3] (3), and [Mn(η 1-pyS)(en)(CO)3] (4). The pyS ligand in these complexes acts as a monodentate, two-electron donor ligand, which coordinates to manganese through the sulfur atom. This is confirmed by an X-ray structure determination of 2, which contains two structural isomers in the asymmetric unit. Crystals of this compound are the monoclinic, space group P2 1/c, a = 21.593(4), b = 10.463(2), c = 16.385(3) Å, β = 102.468(13)°, V = 3614.5(12) Å3, and Z = 8. The three CO groups are facially distributed in both isomers, but the relative positions of the pyS and bipy ligands are different.

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Authors and Affiliations

  1. Department of Chemistry, Jahangirnagar University, Savar, 1342, Dhaka, Bangladesh

    Gulshan Ara, Shariff E. Kabir & Kalipada Kundu

  2. Department of Chemistry, Cardiff University, P. O. Box 912, Park Place, Cardiff, CF10 3TB, United Kingdom

    K. M. Abdul Malik

Authors
  1. Gulshan Ara
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  2. Shariff E. Kabir
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  3. Kalipada Kundu
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  4. K. M. Abdul Malik
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Correspondence to K. M. Abdul Malik.

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Ara, G., Kabir, S.E., Kundu, K. et al. Reactions of [Mn2(μ-pyS)2(CO)6] with bidentate N-donor ligands: Crystal structure of [Mn(η1-pyS)(bipy)(CO)3] (bipy = 2,2′-bipyridyl, pySH = pyridine-2-thiol). Journal of Chemical Crystallography 33, 851–857 (2003). https://doi.org/10.1023/A:1027405729082

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