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Crystal structure of penthylenediammonium pentachlorothallate(III)

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Abstract

The penthylenediammonium pentachlorothallate(III) salt is orthorhombic with the following unit cell dimensions: a = 7.696(3) Å, b = 13.2890(17) Å, and c = 13.503(18) Å, space group P212121 with Z = 4. The structure was solved by Patterson methods and refined to a final R value of 0.0387 for 1991 observed reflections. The structure consists of penthylenediammonium cations and polynuclear anions in which slightly distorted [TlCl6]3− octahedral sharing two vertices are interconnected into chains. These chains are themselves interconnected by means of the N–H⋅⋅⋅Cl bonds originating from the [NH3(CH2)5NH3]2+ entities forming a three-dimensional network.

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Authors and Affiliations

  1. département de chimie, Laboratoire des Sciences de Matériaux et d'Environnement, Tunisia

    M. Abdi, F. Zouari, S. Chaabouni & A. Ben Salah

  2. Faculté des Sciences de Sfax, 3018, Tunisia

    M. Abdi, F. Zouari, S. Chaabouni & A. Ben Salah

Authors
  1. M. Abdi
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  2. F. Zouari
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  3. S. Chaabouni
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  4. A. Ben Salah
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Correspondence to S. Chaabouni.

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Abdi, M., Zouari, F., Chaabouni, S. et al. Crystal structure of penthylenediammonium pentachlorothallate(III). Journal of Chemical Crystallography 33, 839–843 (2003). https://doi.org/10.1023/A:1027401628173

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