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Diffusion Processes in Firing Willemite Glaze on Quartz Glass Ceramics

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Abstract

Diffusion processes occurring at the boundary between willemite glass-ceramic glaze and quartz glass ceramics are considered. Formation of a transitional contact zone between glaze and quartz glass ceramics is experimentally established, which ensures the formation of a strong bond of the coating to the substrate. The extent of the contact zone and the concentration distribution of components in this zone are determined using the method of layer-by-layer pickling and x-ray-fluorescent analysis. Coefficients of mutual diffusion of potassium and silicon ions are calculated for the glaze firing conditions.

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Rudkovskaya, N.V., Mikhailenko, N.Y., Lisinenkova, S.B. et al. Diffusion Processes in Firing Willemite Glaze on Quartz Glass Ceramics. Glass and Ceramics 60, 226–228 (2003). https://doi.org/10.1023/A:1027391209772

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