Abstract
Diffusion processes occurring at the boundary between willemite glass-ceramic glaze and quartz glass ceramics are considered. Formation of a transitional contact zone between glaze and quartz glass ceramics is experimentally established, which ensures the formation of a strong bond of the coating to the substrate. The extent of the contact zone and the concentration distribution of components in this zone are determined using the method of layer-by-layer pickling and x-ray-fluorescent analysis. Coefficients of mutual diffusion of potassium and silicon ions are calculated for the glaze firing conditions.
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REFERENCES
G. N. Maslennikova, “Properties of glazes,” in: VNIIESM. Series: Ceramic Industry [in Russian] (1998).
I. A. Levitskii, E. M. Dyatlova, T. V. Kolontaeva, and V. M. Shelikhina, “Specifics of the formation of a contact zone in a glaze - ceramics system,” Steklo Keram., No. 1, 17–21 (2000).
W. D. Kingery, Introduction to Ceramics [Russian translation], Stroiizdat, Moscow (1967).
N. V. Rudkovskaya and N. Yu. Mikhailenko, “Development of decorative materials with a crystalline structure,” in: Proc. Intern. Conf. “Glass Containers XXI” [in Russian], Gus-Khrustalny (2000), pp. 97–98.
K. K. Evstrop'ev, Diffusion Processes in Glasses [in Russian], Stroiizdat, Leningrad (1970).
A. A. Appen, Chemistry of Glass [in Russian], Khimiya, Leningrad (1970).
O. V. Mazurin, M. V. Strel'tsina, and T. I. Shvaiko-Shvaikovkaya, Properties of Glasses and Glass-Forming Melts, Vol. 3 [in Russian], Nauka, Leningrad (1979).
A. A. Lisinenkov, “Sequence of formation of aluminosilicate and titanium-silicate polyanions in glass formation,” Fiz. Khim. Stekla, 9(4), 426–431 (1983).
V. K. Pavlovskii, “Heterodiffusion in glasses,” Vitreous State, 5, Issue 1, 148–153 (1970).
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Rudkovskaya, N.V., Mikhailenko, N.Y., Lisinenkova, S.B. et al. Diffusion Processes in Firing Willemite Glaze on Quartz Glass Ceramics. Glass and Ceramics 60, 226–228 (2003). https://doi.org/10.1023/A:1027391209772
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DOI: https://doi.org/10.1023/A:1027391209772