Abstract
The kinetics of the coupled internal oxidation of the two most-reactive components in the scaling of ternary alloys under oxidant pressures below the stability of the oxide of the most noble component are examined using a number of simplifying conditions which allow to develop an approximate analytical treatment. The precipitation of the two oxides may occur either at a single front or at two different fronts of internal oxidation. The former case corresponds to a unique solution for all the parameters involved in the process. On the contrary, the existence of two fronts of internal oxidation yields a finite range of possible solutions for the oxidation kinetics as well as for all the other relevant parameters. Even though the present treatment does not allow to predict which solution will be adopted by a real system, it is possible to set limits to the values of the parameters yielding physically-acceptable solutions. After considering a general case, the treatment is applied to a real system already examined experimentally.
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REFERENCES
F. Gesmundo and Y. Niu, Oxid. Met. 60, 347(2003).
F. Gesmundo and Y. Niu, The Internal Oxidation of Ternary Alloys III. To be published.
Y. Niu and F. Gesmundo, The Internal Oxidation of Ternary Alloys IV. To be published.
F. N. Rhines, Trans. Met. Soc. AIME 137, 246(1940).
J. L. Meijering, Internal Oxidation in Alloys, in Advances in Materials Research, H. Herman, ed. (Wiley-Interscience, New York, 1971), Vol. 5, p. 1.
C. S. Giggins and F. S. Pettit, J. Electrochem. Soc. 118, 1782(1971).
H. C. Yi, S. W. Guan, W. W. Smeltzer, and A. Petric, Acta Metall. Mater. 42, 981(1994).
U. Krupp and H. J. Christ, Oxid. Met. 52, 277(1999).
U. Krupp and H. J. Christ, Oxid. Met. 52, 299(1999).
S. W. Guan, H. C. Yi, and W. W. Smeltzer, Oxid. Met. 41, 377(1994).
S. W. Guan, H. C. Yi, and W. W. Smeltzer, Oxid. Met. 41, 389(1994).
J. A. Nesbitt, Oxid. Met. 44, 309(1995).
D. Huin, V. Lanteri, D. Loison, P. Autesserre, and H. Gaye, in Microscopy of Oxidation 3, S. B. Newcomb and J. A. Little, eds. (The Institute of Materials, London, 1997), p. 573.
C. Wagner, Z. Elektrochem. 63, 772(1959).
R. A. Rapp, Corrosion, 21 382(1965).
P. Kofstad, High Temperature Corrosion, (Elsevier Applied Science, New York, 1988).
D. L. Douglass, Oxid. Met. 44, 81(1995).
J. Kirkaldy and D. J. Young, Diffusion in the Condensed State (The Institute of Materials, London, 1987).
K. J. Ronka, A. A. Kodentsov, P. J. J. Van Loon, J. K. Kivilahti, and F. J. J. Van Loo, Metall. Mat. Trans. 27A, 2229(1996).
D. R. Gaskell, Introduction to the Thermodynamics of Materials (Taylor and Francis, Washington, 1995).
J. Crank, Mathematics of Diffusion (Clarendon Press, Oxford, 1965).
P. Bolsaitis and M. Kahlweit, Acta Met. 15, 765(1967).
C. Wagner, Corros. Sci. 8, 889(1968).
Y. Niu, F. Gesmundo, F. Viani, and W. T. Wu, Oxid. Met. 47, 21(1997).
G. Bohm and M. Kahlweit, Acta Met. 12, 641(1964).
F. Gesmundo, P. Castello, F. Viani, and C. Roos, Oxid. Met. 49, 237(1998).
M. Kahlweit, Progr. Solid State Chem. 2, 134(1965).
J. Park and C. J. Altstetter, Met. Trans. 18A, 43(1987).
R. A. Swalin, A. Martin, and R. Olson, J. Metals 9, 936(1957).
W. Gust, M. B. Hints, A. Lodding, H. Odelius, and B. Predel, Phys. Stat. Sol. 64, 187(1981).
I. Barin, Thermochemical Data of Pure Substances (VCH, Weinheim, Germany, 1989).
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Niu, Y., Gesmundo, F. The Internal Oxidation of Ternary Alloys II: The Coupled Internal Oxidation of the Two Most-Reactive Components Under Intermediate Oxidant Pressures. Oxidation of Metals 60, 371–391 (2003). https://doi.org/10.1023/A:1027379521347
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DOI: https://doi.org/10.1023/A:1027379521347